Journal ArticleDOI
Sodium-hydrogen interdiffusion in sodium silicate glasses
TLDR
In this article, the authors used sputter-induced photon spectrometry technique (SIPS) to measure the depth profiles of hydrogen and sodium in Na2O · 3 SiO2 glasses and determined the thickness of the hydrated layers as functions of time and temperature.Abstract:
The hydration of Na2O · 3 SiO2 glasses is studied using the sputter-induced photon spectrometry technique (SIPS) to measure the depth-profiles of hydrogen and sodium. The results clearly show a penetration of hydrogen and a leaching of sodium in the glass. The thicknesses of the hydrated layers are determined as functions of time and temperature. The thicknes dependence on the square root of time indicates that a diffusion process is in operation. The data are fitted to he Doremus model of interdiffusing ions and the diffusion coefficients for hydrogen and sodium are calculated.read more
Citations
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Journal ArticleDOI
Diffusion of water in rhyolitic glasses.
TL;DR: The activation energy for diffusion in rhyolitic glasses is well correlated with neutral species radii of He, Ne, H2O, and Ar, and supports the contention that the diffusing species for "water" is neutral molecular H 2O.
Journal ArticleDOI
Chemical durability of glasses
TL;DR: In this article, it is shown that during leaching the structure of the glass is changed and the moving particles are altered, which means that some fundamentals for applying the usual diffusion equations are not valid.
Journal ArticleDOI
Silicate melt properties and volcanic eruptions
TL;DR: In this article, the role of speciation in the solubility and diffusivity of H2O and CO2 in silicate melts has been investigated, and the results showed that the complexity in the diffusion behavior of H 2O and the simplicity of CO2 are due to differences in the speciation reaction.
Journal ArticleDOI
Diffusion of H, C, and O Components in Silicate Melts
Youxue Zhang,Huaiwei Ni +1 more
TL;DR: In this article, the diffusion of H, C and O components in a melt is reviewed and a review of different kinds of diffusion methods is presented, such as self-diffusion, tracer diffusion, effective binary diffusion and multi-component diffusion.
Journal ArticleDOI
Mechanisms for alkali leaching in mized-NaK silicate glasses
TL;DR: In this article, the authors studied the kinetics of leaching from (1-X) Na2O·XK 2O·3SiO2 glasses using pH stat titration techniques, solution analyses and elemental depth profiling by Rutherford backscattering spectrometry and elastic recoil detection.
References
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Journal ArticleDOI
Interdiffusion of hydrogen and alkali ions in a glass surface
TL;DR: In this paper, experimental data on the interdiffusion of hydrogen and alkali ions in glass were examined using a concentration-dependent inter-diffusion coefficient, taking into account surface dissolution.
Journal ArticleDOI
Hydration of soda-lime glass
TL;DR: In this article, the hydration of soda-lime glass is studied using resonant nuclear reactions to measure the hydrogen and sodium profiles of hydrated glasses, and the measured hydration profiles are discussed in relationship to the Doremus model of interdiffusing ions.
Book
Corrosion of glass
TL;DR: In this article, the compositional and structural changes on surfaces that affect the durability of soda-limesilica glasses are discussed and a general review of corrosion and weathering phenomena in glass is presented.
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Aqueous Corrosion of Soda‐Silica and Soda‐Lime‐Silica Glass
Journal ArticleDOI
Characterization of glass corrosion and durability
TL;DR: In this paper, the surface and bulk structural state of a glass object is described in terms of intrinsic structural features, i.e., the structural changes in the bulk or surface structure of the glass due to processing or environmental conditions.