Journal ArticleDOI
Solubilization of alkali metals in tetrahydrofuran and diethyl ether by use of a cyclic polyether
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This article is published in Journal of the American Chemical Society.The article was published on 1970-08-01. It has received 68 citations till now. The article focuses on the topics: Tetrahydrofuran & Diethyl ether.read more
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Theoretical study on alkali-metal doped N3H3 complexes: an in-depth understanding of the origin of electride and alkalide and their large nonlinear optical properties.
TL;DR: It was found that both thecomplexant–complexant and the complexant–Li’ interactions reduced with the addition of N3H3 layers, so no stable structures were found for larger Li(N 3H3)nLi�’ complexes.
Journal ArticleDOI
Novel ring opening polymerization induced by alkali metal anions
TL;DR: In this article, a homogeneous initiation system consisting of organic alkali metal complexes, Me+/Ligand, Me− enable synthesis of "living" tailor made polymers and copolymers promising materials for engineering and biomedical applications.
Journal ArticleDOI
Novel electron transfer polymerization processes with alkali metal supramolecular complex as catalyst
TL;DR: In this article, the capability of these solutions of transferring two electrons to a suitable organic substrate and formation of corresponding carbanions opens new door in synthetic chemistry, and reactions of some vinyl compounds, alkyl and silyl halides, as well as ring-opening polymerization of β-lactones and oxiranes are discussed.
Book ChapterDOI
Chapter 1 – Chemical synthesis of nanostructured metals, metal alloys, and semiconductors
TL;DR: In this paper, the authors outline several common and unique techniques for the synthesis of nanostructured materials (NSMs), intermetallics, and semiconductors in powder and thin-film form.
Journal ArticleDOI
Physicochemical studies of alkali metal solutions in tetrahydrofuran.
Jacques Lagoste,Francois Schué +1 more
TL;DR: In this article, the authors studied the rate of alkali metal dissolution in THF as a function of its nature and of the cryptand (C), and estimated the selectivity through the equilibrium constant of the following equilibrium:M−+C\leftrightarrowsM+C+2esolv.