Journal ArticleDOI
Solubilization of alkali metals in tetrahydrofuran and diethyl ether by use of a cyclic polyether
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This article is published in Journal of the American Chemical Society.The article was published on 1970-08-01. It has received 68 citations till now. The article focuses on the topics: Tetrahydrofuran & Diethyl ether.read more
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Book ChapterDOI
Complex formation of monovalent cations with biofunctional ligands.
Journal ArticleDOI
Chemistry of crown ethers: Synthesis of crown ethers based on α,β-bis(halomethyl)- or α,β-bis(hydroxymethyl)-substituted aromatics
TL;DR: In this paper, a template effect of the cation in the cyclization step was found to explain the relatively high yields of these macrocyclic polyethers (rings containing from 11 to 34 atoms), obtained without operating at high dilution, depend both on the chain length of the glycol and on the nature of the Cation.
Journal ArticleDOI
Total Syntheses of Multiple Cladiellin Natural Products by Use of a Completely General Strategy
J. Stephen Clark,Raphaëlle Berger,Stewart T. Hayes,Hans Martin Senn,Louis J. Farrugia,Lynne H. Thomas,Angus J. Morrison,Luca Gobbi +7 more
TL;DR: The enantioselective total syntheses of 10 cladiellin natural products have been completed, starting from the known allylic alcohol (+)-14, which can be prepared in large quantities.
Book ChapterDOI
Electrochemistry of solvated electrons
TL;DR: In this article, a review of theoretical concepts of the electrochemical properties of solvated electrons and the results of experimental studies are considered from a unified position, including energy levels of localized (solvated) and delocalized electrons in solutions and methods for their determination.