Journal ArticleDOI
Some aspects of anion-induced adsorption of white metal cations on mercury
Donald J. Barclay,Fred C. Anson +1 more
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In this article, it was shown that the neutral cation-anion complex (PbCl3− being the single known exception to this rule) is usually the neutral ion complex and that in the course of adsorption the coordination number of the metal ion increases as it forms additional bonds with anions which are specifically adsorbed on the mercury electrode.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1970-11-01. It has received 77 citations till now. The article focuses on the topics: Dropping mercury electrode & Adsorption.read more
Citations
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The influence of electrolyte concentration on the parameters of the Frumkin isotherm in the Cd2+–I− system
Marina Zelić,Milivoj Lovrić +1 more
TL;DR: In this article, the influence of ionic strength on the parameters of adsorption isotherm(s) was studied using Cd2+−I− system as a model.
Journal ArticleDOI
On the influence of adsorption of electroactive species on the polarographic determination of stability constants
M. C. Montemayor,Enrique Fatás +1 more
TL;DR: In this article, the influence of specific adsorption of electroactive species on the polarographic determination of stability constants is studied quantitatively, and an expression for the term that permits correction of the effect of the advertisersorption and the "true" value of the constants to be obtained from the apparent value is deduced.
Journal ArticleDOI
Spherical aggregates composed of gold nanoparticles.
TL;DR: The results indicate that the morphology of the reduced gold nanoparticles is controllable through pH-'tunable' aggregation under the mediation of the amino groups of alkylated amine to create spherical microstructures.
Journal ArticleDOI
Influence of anion-induced adsorption on the polarographic/voltammetric determination of stability constants
Marina Zelić,Marko Branica +1 more
TL;DR: In this article, the polarographic/voltammetric determination of complexation constants, influenced by ligand-induced adsorption of metal ions, was studied and the factors affecting the final results, such as the speed of the applied technique, metal concentration, ionic strength and data treatment were examined, taking lead and cadmium(II) in halide solutions as model systems.
Journal ArticleDOI
Adsorptive stripping square-wave voltammetry of Bi(III) in chloride media. Influence of triton X-100
TL;DR: In this article, the adsorption of bismuth(III) ions in submicromolar concentrations is analyzed by square-wave voltammetry in the cathodic stripping mode.
References
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Journal ArticleDOI
Components of Charge and Potential in the Inner Region of the Electrical Double Layer: Aqueous Potassium Chloride Solutions in Contact with Mercury at 25°
David C. Grahame,Roger Parsons +1 more
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On the impedance of galvanic cells
TL;DR: In this article, a critical discussion is presented of some important theories for the electrode impedance in the case that the electroactive species are specifically adsorbed at the electrode-solution interface.
Journal ArticleDOI
Application of double potential-step chronocoulometry to the study of reactant adsorption. theory
TL;DR: In this paper, the theory of a new technique for the study of reactant adsorption is developed and it is shown that a rigorous double-layer correction can be made and that a quantitative determination of the amount of adorption was possible.
Journal ArticleDOI
Adsorption of sulphur-containing species at the mercury/water interphase
Roger Parsons,P. C. Symons +1 more
TL;DR: The adsorption of SCN- ions and thiourea has been investigated by measuring the capacity of a mercury electrode as discussed by the authors, where the apparent dielectric constant passes through a maximum at a charge on the electrode of about + 6µC cm−2.
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