Journal ArticleDOI
Some aspects of anion-induced adsorption of white metal cations on mercury
Donald J. Barclay,Fred C. Anson +1 more
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In this article, it was shown that the neutral cation-anion complex (PbCl3− being the single known exception to this rule) is usually the neutral ion complex and that in the course of adsorption the coordination number of the metal ion increases as it forms additional bonds with anions which are specifically adsorbed on the mercury electrode.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1970-11-01. It has received 77 citations till now. The article focuses on the topics: Dropping mercury electrode & Adsorption.read more
Citations
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Self-Organization of Nanosized Gold Particles
TL;DR: In this paper, a quaternary ammonium bromide salt (R4N+Br-) is specifically adsorbed on the colloidal gold solutions through the formation of surface ion pairs, probably with the Br- ion attached to the Au surface.
Journal ArticleDOI
Mercury-free simultaneous determination of cadmium and lead at a glassy carbon electrode modified with multi-wall carbon nanotubes
TL;DR: In this article, a multi-wall carbon nanotube (MWNT) modified glassy carbon electrode (GCE) was described for the simultaneous determination of trace levels of cadmium and lead by anodic stripping voltammetry (ASV).
Journal Article
Some mechanisms of the action of additives in electrodeposition processes
TL;DR: A review of mechanisms by which additives have been postulated to affect the rate of deposition of metals and their alloys can be found in this article, where the possible role of electrode filming in electrodeposition of difficult-to-plate metals is discussed, as well as anomalous and induced codeposition of alloys, and deposition of stoichiometric alloys.
Journal ArticleDOI
Some mechanisms of action of additives in electrodeposition processes
TL;DR: A review of the mechanisms by which additives have been postulated to affect the rate of deposition of metals is given in this article, including blocking the surface, changing the Helmholtz potential, complex formation, ion pairing, changes in interfacial tension and filming of the electrode, hydrogen evolution effects, hydrogen absorption, anomalous codeposition and the effect on intermediates.
References
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Journal ArticleDOI
The Adsorption of Aromatic Sulfonates at a Mercury Electrode II . Sodium p‐Toluenesulfonate—An Example of Two‐Position Adsorption
J. M. Parry,R. Parsons +1 more
Journal ArticleDOI
A study of the adsorption of cadmium(II) on mercury from thiocyanate solutions by double potential-step chronocoulometry
TL;DR: In this article, the double potential-step chronocoulometric method was used to determine the adsorption of Cd(II) in thiocyanate solutions.
Journal ArticleDOI
Electrochemical data acquisition and analysis system based on a digital computer
Journal ArticleDOI
Chronopotentiometric and Chronocoulometric Measurements of Adsorption of Lead and Mercury(II) at Mercury Electrodes.
Royce W. Murray,Donald J. Gross +1 more
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Chronocoulometric measurement of indium(III) adsorption from thiocyanate medium
George W. O'Dom,Royce W. Murray +1 more
TL;DR: In this article, the adsorption of indium(III) at a mercury electrode from acidified thiocyanate medium has been quantitatively characterized using the chronocoulometric technique.
Related Papers (5)
Anion induced adsorption of cadmium(II) on mercury from iodide and bromide media
Fred C. Anson,Donald J. Barclay +1 more
Chronocoulometric measurement of indium(III) adsorption from thiocyanate medium
George W. O'Dom,Royce W. Murray +1 more
Influence of anion-induced adsorption on half-wave potentials and other polarographic characteristics
Alan M. Bond,Glenn Hefter +1 more