Some reactions occurring between KSCN and molten NaNO3KNO3
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TLDR
When KSCN is added to molten NaNO 3 KNO 3 eutectic within the range of 230-316°C, a complex and a relatively violent chemical reaction takes place as mentioned in this paper.About:
This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1974-08-01 and is currently open access. It has received 2 citations till now. The article focuses on the topics: Chemical reaction & Eutectic system.read more
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Corrosion of nickel, iron, cobalt and their alloys in molten salt electrolytes
TL;DR: In this paper, the processes of high-temperature corrosion, anodic dissolution and passivation of nickel, iron, cobalt and their alloys are reviewed to reveal the progress in understanding the reaction mechanisms defined in the last two decades.
References
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Redox chemistry of the system O2-O2--O22--O2- in fused salts
Pier G. Zambonin,Joseph Jordan +1 more
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Studies of Acid—Base Equilibria in Molten Alkali Nitrates
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Oxide chemistry and electroreduction of NO3− in molten alkali nitrates
TL;DR: In this paper, microcoulometric and voltammetric measurements have been carried out in the temperature range 229°-280°C in a (Na,K)NO3 eutectic melt, pure or containing species produced in situ by massive electrolysis.
Journal ArticleDOI
Remarkable redox equilibria in fused salts
TL;DR: In this paper, the superoxide species O2−, normally considered a transient free radical, can coexist indefinitely in equilibrium with O2, O22− and NO2−.
Journal ArticleDOI
Thermodynamics of iron/molten-sodium-nitrate
TL;DR: In this article, potential/pO 2− diagrams have been developed for the iron/molten-sodium-nitrate system at 600 and 700°K, and four well defined regions corresponding respectively to metal corrosion, immunity, passivity and passivity breakdown are shown in the diagrams.