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Spectrometric Study of Shock-Heated Mg/MgO Particle Dispersions

TLDR
In this paper, a premixed metal vapor-oxygen system for studying these kinetics was approximated by the combination of a shock tube with an exploding Mg wire particle generator.
Abstract
Homogeneous kinetics may play a large role in dictating diffusion flame structure for metals like Mg. A premixed metal vapor-oxygen system for studying these kinetics was approximated by the combination of a shock tube with an exploding Mg wire particle generator. This portion of the study was unsuccessful because the experimental data indicate the dispersion to consist of MgO rather than Mg particles. A kinetic mechanism is postulated which is consistent with the spectrometric observations. Certain wave interactions in the shock tube which severely curtail experimental times behind the reflected shock are also discussed.

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Combustion of Magnesium with Carbon Dioxide and Carbon Monoxide at Low Gravity

TL;DR: In this paper, the burning behavior and ame structure of magnesium in pure carbon dioxide and pure carbon monoxide atmospheres in low-gravity conditions were investigated, showing that the burning time is proportional to the square of the metal sample diameter.
Journal ArticleDOI

Experimental and numerical investigations on the decomposition and combustion characteristics of composite propellant with Mg/Al particles additives

TL;DR: In this article, a detailed combustion kinetic model was employed in the in-house computational solver to simulate this typical two-phase flow problem, and the combustion phenomenon was analyzed carefully about flame structure, chemical reaction order, and an obvious double-platform phenomenon was observed in the temperature distributions of combustion wave on central axis.
Journal ArticleDOI

Numerical study of MgO powder synthesis by thermal plasma

TL;DR: In this article, a numerical model for homogeneous nucleation and growth of MgO particles in a thermal plasma reactor is presented, and the results indicate that the number of particles nucleated is a function of initial Mg concentration and cooling rate in the nucleation region.
Journal ArticleDOI

High-temperature fast-flow reactor studies ofmetal-atom oxidation kinetics

TL;DR: The tubular fast-flow reactor has been adapted to reach temperatures up to 2000°K, and has been applied to studies of gas-phase reactions of metal atoms with O 2, with the most extensive results obtained so far is for the Fe/O 2 reaction in a N 2 bath at 1600°K as discussed by the authors.
References
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JANAF thermochemical tables

Journal ArticleDOI

Absorption spectrum of the Mg2 molecule

TL;DR: In this article, the absorption spectrum of the Mg2 molecule, which occurs in a furnace containing Mg vapor, has been photographed with a high resolution spectrograph, and the rotational structures of the bands have been analyzed.
Journal ArticleDOI

Ultraviolet Bands of Magnesium Hydroxide and Oxide

TL;DR: The molecular species responsible for the ultraviolet bands of ''magnesium oxide'' have been shown to be MgOH and MgO as discussed by the authors, which are the major contributors to the thermodynamic functions of gases at high temperatures.
Journal ArticleDOI

Techniques for the study of the combustion of metals

TL;DR: Techniques for study of metal combustion in rocketry including particle burning, bulk metal and metal vapor combustion and low temperature oxidation are described in detail in this paper, where the authors present a detailed review of the literature.
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