Journal ArticleDOI
Stereo- and regiochemistry in palladium-catalyzed nucleophilic substitution of optically active (E)- and (Z)-allyl acetates
TLDR
In this article, the reactions des cis-and trans-acetates des phenyl-4 butene-3ol-2 and phenyl -1 butene 2ol-1 avec le sodiomalonate de dimethyle, l'acetylacetonate de sodium and le sodioacetylacetate de methyle en presence d'un catalyseur au palladium.Abstract:
Etude des reactions des cis- et trans-acetates des phenyl-4 butene-3ol-2 et phenyl-1 butene-2ol-1 avec le sodiomalonate de dimethyle, l'acetylacetonate de sodium et le sodioacetylacetate de methyle en presence d'un catalyseur au palladiumread more
Citations
More filters
Journal ArticleDOI
Asymmetric Transition Metal-Catalyzed Allylic Alkylations.
TL;DR: The focus of this review is on the area of enantioselective transition metal-catalyzed allylic alkylations which may involve C-C as well as C-X (X ) H or heteroatom) bond formation.
Journal ArticleDOI
Non-Metathesis Ruthenium-Catalyzed C−C Bond Formation
Journal ArticleDOI
Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds
TL;DR: This work states that the stereocontrolled construction of C−C bonds remains one of the foremost challenges in organic synthesis and has resulted in a paradigm shift in synthetic strategy planning.
Journal ArticleDOI
Bite angle effects of diphosphines in C-C and C-X bond forming cross coupling reactions.
TL;DR: Catalytic reactions of C-C and C-X bond formation are discussed in this critical review with particular emphasis on cross coupling reactions catalyzed by palladium and wide bite angle bidentate diphosphine ligands.
Journal ArticleDOI
Selectivity in palladium catalysed allylic substitution
TL;DR: Palladium catalysed allylic substitution has emerged as one of the more useful synthetic methods for the construction of C-C and C-X bonds as mentioned in this paper, which offers the advantages of mild reaction conditions, as well as the ability to accomodate a wide range of nucleophiles and their electrophilic partners.