Journal ArticleDOI
Stereochemically nonrigid carbonyl complexes of group VIII B metal clusters
Reads0
Chats0
TLDR
In this paper, the variable temperature 13 C-nmr of M 3 (CO) 12 (M = Fe, Ru, Os) have been studied and the importance of bridging intermediates in this exchange process is discussed.About:
This article is published in Inorganica Chimica Acta.The article was published on 1975-01-01. It has received 53 citations till now. The article focuses on the topics: Ruthenium & Osmium.read more
Citations
More filters
Journal ArticleDOI
Relationships between structure and ligand dynamics: II. Alkyne and carbonyl dynamics in Os3(CO)9(alkyne)(L) (L = CO, PR3)
Edward Rosenberg,Julia. Bracker-Novak,Robert W. Gellert,Silvio Aime,Roberto Gobetto,Domenico Osella +5 more
TL;DR: In this article, a detailed analysis of the VT-1H and VT-13C NMR of these complexes is presented and compared with the same studies on the parent complexes Os3(CO)9(μ3-η2-RCCR)(μ-CO) (R = CH2CH3 (I), CH3 (II)).
Journal ArticleDOI
Synthesis and Crystal Structure of Undecacarbonyl (triphenylphospine)-triangulo-triruthenium, Ru3(CO)11Ph3P
TL;DR: In this article, X-ray structure determination of the cluster compound reveals a single isomer in which there is a triangle of ruthenium atoms with the triphenylphosphine equatorially substituted and all the carbonyl groups terminally sited.
Journal ArticleDOI
Reactions of ruthenium carbonyl clusters with alkynes
TL;DR: An overview of the work performed at the University of Turin in the last 25 years on the reactivity of Ru3(CO)12 with alkynes and related reactions is given in this paper.
References
More filters
Journal ArticleDOI
Carbon-13 nuclear magnetic resonance spectra of metal carbonyl compounds
Lee J. Todd,John R. Wilkinson +1 more
Journal ArticleDOI
Further refinement of the molecular structure of triiron dodecacarbonyl
F. Albert Cotton,Jan M. Troup +1 more
Journal ArticleDOI
Dodecacarbonyltriiron: analysis of its stereochemistry
Chin Hsuan Wei,Lawrence F. Dahl +1 more
Journal ArticleDOI
Temperature-dependent carbon-13 nuclear magnetic resonance spectra of the h5-cyclopentadienyliron dicarbonyl dimer, an application of a shiftless relaxation reagnet
Journal ArticleDOI
The Molecular and Crystal Structure of Os3(CO)12
Eugene R. Corey,Lawrence F. Dahl +1 more
Related Papers (5)
Further refinement of the molecular structure of triiron dodecacarbonyl
F. Albert Cotton,Jan M. Troup +1 more