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Stereochemically nonrigid carbonyl complexes of group VIII B metal clusters

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TLDR
In this paper, the variable temperature 13 C-nmr of M 3 (CO) 12 (M = Fe, Ru, Os) have been studied and the importance of bridging intermediates in this exchange process is discussed.
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This article is published in Inorganica Chimica Acta.The article was published on 1975-01-01. It has received 53 citations till now. The article focuses on the topics: Ruthenium & Osmium.

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Relationships between structure and ligand dynamics: II. Alkyne and carbonyl dynamics in Os3(CO)9(alkyne)(L) (L = CO, PR3)

TL;DR: In this article, a detailed analysis of the VT-1H and VT-13C NMR of these complexes is presented and compared with the same studies on the parent complexes Os3(CO)9(μ3-η2-RCCR)(μ-CO) (R = CH2CH3 (I), CH3 (II)).
Journal ArticleDOI

Synthesis and Crystal Structure of Undecacarbonyl (triphenylphospine)-triangulo-triruthenium, Ru3(CO)11Ph3P

TL;DR: In this article, X-ray structure determination of the cluster compound reveals a single isomer in which there is a triangle of ruthenium atoms with the triphenylphosphine equatorially substituted and all the carbonyl groups terminally sited.
Journal ArticleDOI

Reactions of ruthenium carbonyl clusters with alkynes

TL;DR: An overview of the work performed at the University of Turin in the last 25 years on the reactivity of Ru3(CO)12 with alkynes and related reactions is given in this paper.
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