Journal ArticleDOI
Structures and stabilities of α-hetero-substituted organolithium and organosodium compounds. Energetic unimportance of d-orbital effects
Paul von Ragué Schleyer,Timothy Clark,Alexander J. Kos,Günther W. Spitznagel,Cornelia Rohde,Dorit Arad,K. N. Houk,Nelson G. Rondan +7 more
TLDR
In this article, the authors composes MCH 2 X avec M=Li ou Na et X=CH 3, NH 2, OH, F, SiH 3, PH 2, SH ou Cl, avec corrections de correlation electronique.Abstract:
Calculs ab initio sur les composes MCH 2 X avec M=Li ou Na et X=CH 3 , NH 2 , OH, F, SiH 3 , PH 2 , SH ou Cl, avec corrections de correlation electronique. Comparaison avec especes anioniques correspondantesread more
Citations
More filters
Journal ArticleDOI
The Structure of Lithium Compounds of Sulfones, Sulfoximides, Sulfoxides, Thioethers and 1,3-Dithianes, Nitriles, Nitro Compounds and Hydrazones
TL;DR: In this article, the authors summarize recent research into the structures of the acceptor-substituted lithio compounds of sulfones, sulfoximides, sulfoxide, thioethers and 1,3-dithianes, nitriles, nitro compounds, and hydrazones.
Journal ArticleDOI
The electrophilic nature of carbenoids, nitrenoids, and oxenoids.
Gernot Boche,John C. W. Lohrenz +1 more
Journal ArticleDOI
Cationic Metallocene Polymerization Catalysts Based on Tetrakis(pentafluorophenyl)borate and Its Derivatives. Probing the Limits of Anion “Noncoordination” via a Synthetic, Solution Dynamic, Structural, and Catalytic Olefin Polymerization Study
TL;DR: In this paper, the synthesis and properties of two soluble, weakly coordinating derivatives of the tetrakis(perfluoroaryl)borate anion B(4-C6F4TBS)4 and B( 4-C 6F4TIPS)4- (TBS = tert-butyldimethylsilyl and TIPS = triisopropyl silyl) are reported.
Journal ArticleDOI
Homoleptic Rare-Earth Metal Complexes Containing Ln−C σ-Bonds†
TL;DR: Catalytic activities and stereoselectivities are influenced by the length of the linker between the cyclopentadienyl and the amido-functionality and the substituents at the amidonitrogen.
Related Papers (5)
13C‐NMR.‐Spektroskopie von Organolithiumverbindungen bei tiefen Temperaturen. Strukturinformation aus der 13C, 6Li‐Kopplung
Stereoelectronic effects. 5. Stereoelectronic properties, stereospecificity, and stabilization of .alpha.-oxa and .alpha.-thia carbanions
Jean-Marie Lehn,Georges Wipff +1 more