Journal ArticleDOI
Study of the thermal decompositions of some transition metal perchlorates
Frigyes Solymosi,J. Raskó +1 more
TLDR
In this article, the thermal decomposition of manganese perchlorates was studied by thermal analysis and kinetic measurements, and a correlation was found between the stabilities of the perchlorate and the effective field strengths of the cations.Abstract:
The thermal decompositions of nickel(II), copper(II), cobalt(II) and manganese(II) perchlorates were studied by thermal analysis and kinetic measurements. Anhydrous perchlorates could not be prepared by heating and outgassing the samples in vacuum; oxides were obtained as the main solid decomposition products. In the case of cobalt and manganese perchlorates, oxidation of the metal ions was observed during the decomposition. In most cases the decompositions of the perchlorates followed the Avrami-Erofeyev kinetics. A correlation was found between the stabilities of the perchlorates and the effective field strengths of the cations.read more
Citations
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Journal ArticleDOI
Thermal decomposition of potassium, rubidium and caesium fluoroantimonates(III)
TL;DR: In this article, the thermal decomposition of crystalline complexes of the types M2[SbF5], M[SfF4], Mf4, Mf2F7] and Mf1F13, where M = K, Rb, Cs, was studied.
Journal ArticleDOI
Effects of gas-phase mass transport in the pyrotechnic system red lead-silicon-potassium perchlorate
TL;DR: In this article, the acceleratory effect of potassium perchlorate on the reactivity of the red lead-silicon system has been studied by employing DTA and DSC.
Journal ArticleDOI
Green and Energy-Saving Recycling of LiCoO2 by Synergetic Pyrolysis with Polyvinyl Chloride Plastics
Zhe Meng,Weiwei Huang,Lei Gao,Jinchuan Dai,Xiao-Ying Lu,Jiadong Liu,Kaimin Shih,Yu-chao Tang +7 more
TL;DR: Li et al. as mentioned in this paper proposed a polyvinyl chloride (PVC) synergetic pyrolysis strategy for Li/Co recovery, which showed that LiCoO2 was fully destructed to Li2CO3, CoO, Co, and Cl-containing salts at 450 °C for 90 min with a PVC/LCO mass ratio of 1:1.
Journal ArticleDOI
Solvent-Free Synthesis of Nickel Nanoparticles as Catalysts for CO2 Hydrogenation to Methane
O. V. Netskina,K. A. Dmitruk,A. A. Paletsky,S.A. Mukha,A.A. Pochtar,Olga A. Bulavchenko,Igor P. Prosvirin,Andrey G. Shmakov,Anna M. Ozerova,Janna V. Veselovskaya,Olga I. Mazina,O.V. Komova +11 more
TL;DR: In this paper , the solid-state combustion method was used to prepare nickel-based catalysts for CO2 hydrogenation from [Ni(C3H4N2)6]-NO3)2 and [Ni[C 3H 4N2]6]-ClO4)2.
Journal ArticleDOI
{[NiL][Co(NCS)4]} n , an organic–inorganic coordination polymer (L = 5,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)
TL;DR: The organic-inorganic coordination polymer of the general formula {[NiL][Co(NCS)4]n (where L = 5,12-dimethyl-1,4,8,11tetraazacyclotetradeca-4,11-diene) has been synthesized and characterized by IR, UV-Vis, DSC/TG, DTA/TG/MS methods.
References
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Book
Handbuch der anorganischen Chemie
TL;DR: A detailed account of the complex cyanides of iron with a bibliography which includes 1,360 references was given by Hirzel as discussed by the authors, where the frontispiece is a reproduction of early references to Prussian blue by an anonymous writer in 1710, by Woodward and by Brown in the Philosophical Transactions of 1724 and by Stahl in 1731.
Journal ArticleDOI
The thermal decomposition of magnesium perchlorate and of ammonium perchlorate and magnesium perchlorate mixtures
Journal ArticleDOI
Thermal Decomposition of Perchlorates
Journal ArticleDOI
Catalytic decomposition of perchloric acid vapor on zinc oxide
Frigyes Solymosi,L. Gera +1 more
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