Substitution reactions of metallic complexes of β,β′,β″-triaminotriethylamine—IX: Kinetics of acid hydrolysis of dichloro(triaminotriethylamine) rhodium(III) ion

doi:10.1016/0022-1902(75)80148-5

Journal ArticleDOI

Substitution reactions of metallic complexes of β,β′,β″-triaminotriethylamine—IX: Kinetics of acid hydrolysis of dichloro(triaminotriethylamine) rhodium(III) ion

Sybil G. Zipp, +1 more

- 01 Jan 1975 -

Journal of Inorganic and Nuclear Chemist...

- Vol. 37, Iss: 1, pp 181-184

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TLDR

In this paper, the authors studied the kinetics of primary acid hydrolysis reaction of [Rh(tren)Cl 2 ] + ion [tren = β,β′,β″-triaminotriethylamine, N(CH 2 CH 2 NH 2 ) 3 ] between 25 and 60·3°.

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This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1975-01-01. It has received 2 citations till now. The article focuses on the topics: Hydrolysis constant & Aquation.

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Journal ArticleDOI

Mechanistic studies on rhodium(iii) chelates. aquation of cis‐dihalobisbiguaniderhodium(iii) nitrates

Biswanath Chakravarty, +1 more

- 01 Jan 1977 -

Inorganica Chimica Acta

TL;DR: In this article, the first and second halide ions were derived by a graphical method and the rates of release of the first ion and second ion were derived using the Eyring equation.

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Journal ArticleDOI

Substitution reactions of metallic complexes of 2,2′,2″-triaminotriethylamine. XVI. Kinetics of the (oxalato)(2,2′,2″-triaminotriethylamine) cobalt(III) cation in dilute and concentrated acid

Mthembeni M. Zulu, +1 more

- 15 Jul 1988 -

Inorganica Chimica Acta

TL;DR: In this article, the authors investigated the kinetics of the stepwise reactions of [Co(tren)C2O4]+ ion in both dilute and concentrated acids, as well as the characterization in solution of some new Co(III) tren complexes.

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