Journal ArticleDOI
Symmetrically disubstituted ferrocenes
TLDR
The 1,1′-dilithioferrocene can be used in situ, or when isolated as the pyrophoric adduct [(C 5 H 4 Li) 2 Fe]·TMEDA, to prepare the following complexes in high yields: ferrocene-1, 1, 1′-bis(dimethylarsine) (Fdma), ferrocenophane, Fdpa, Fdt, Fydioxene, and Fdmp, which can be converted quantitatively to Fdt by reduction with lithium aluminum hydrAbout:
This article is published in Journal of Organometallic Chemistry.The article was published on 1971-03-01. It has received 369 citations till now. The article focuses on the topics: 1,1'-Bis(diphenylphosphino)ferrocene & Tetramethylethylenediamine.read more
Citations
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Linear Oligo(ferrocenyldimethylsilanes) with between Two and Nine Ferrocene Units: Electrochemical and Structural Models for Poly(ferrocenylsilane) High Polymers
TL;DR: In this paper, three series of oligo(ferrocenylsilanes) R-fc]-SiMe2-fc]n-1-R‘ (fc = Fe(η-C5H4)2) 72−79 (R = R‘ = H), 82−87 (R= H and R´ = SiMe3), and 92−97
Journal ArticleDOI
Polyferrocenylsilanes: synthesis, properties, and applications
TL;DR: This in-depth review covers progress in the area of polyferrocenylsilanes (PFS), a well-established, readily accessible class of main chain organosilicon metallopolymer consisting of alternating ferrocene and organosILane units.
Journal ArticleDOI
Strained metallocenophanes and related organometallic rings containing π-hydrocarbon ligands and transition-metal centers
TL;DR: This Review summarizes the current state of knowledge on the preparation, structural characterization, electronic structure, and reactivity of strained organometallic rings with pi-hydrocarbon ligands and d-block metals.
Book ChapterDOI
Ring-Opening Polymerization of Metallocenophanes: A New Route to Transition Metal-Based Polymers†
Journal ArticleDOI
Diiron Oxadithiolate Type Models for the Active Site of Iron-Only Hydrogenases and Biomimetic Hydrogen Evolution Catalyzed by Fe2(μ-SCH2OCH2S-μ)(CO)6
TL;DR: In this article, the biomimetic chemistry of single and double oxadithiolatodiiron-containing model compounds for the active site of Fe-only hydrogenases (FeHases) has been systematically studied.
References
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Gauche effect. Stereochemical consequences of adjacent electron pairs and polar bonds
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Organometallic π-complexes XII. The metalation of benzene and ferrocene by n-butyllithium-N,N,N′,N′-tetramethylethylenediamine
TL;DR: In this paper, a detailed study has been made concerning the metalation of benzene and ferrocene by means of n-butyllithium + N,N,N′, N′-tetramethylethylenediamine in hexane and ethyl ether solution.
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The Structure and Chemistry of Ferrocene. VII. Bridged Ferrocenes
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