Journal ArticleDOI
Synthesis and Dynamic NMR Studies of Pentafluorobenzenethiolate Complexes of Molybdenum and Tungsten. The Crystal and Molecular Structures of (W(SC6F5)3(CO)(η5-C5H5))·0.5 CH2Cl2 and (N(PPh3)2)(Mo(SC6F5)4(η5-C5H5)).
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This article is published in ChemInform.The article was published on 1990-04-10. It has received 1 citations till now. The article focuses on the topics: Molybdenum & Tungsten.read more
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Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]·0.5CH2Cl2and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, it was shown that the reaction between [WBr3(CO)2(η5-C5H5)] and excess of Tl(SC6F5)(CH2Cl2, 20 °C) affords Tl[W(SC 6F5)4( η5 −C5 −H5)