Journal ArticleDOI
Synthetic Methods and Reactions; 76.1 Deoxygenation of Sulfoxides with Sodium Iodide/Iodine/Trimethyl(ethyl)amine/Sulfur Dioxide or Sodium Iodide/Pyridine/Sulfur Trioxide Complexes
Reads0
Chats0
About:
This article is published in Synthesis.The article was published on 1979-01-01. It has received 18 citations till now. The article focuses on the topics: Sulfur trioxide & Deoxygenation.read more
Citations
More filters
Journal ArticleDOI
Palladium-Catalyzed Aminosulfonylation of Aryl Halides
TL;DR: The palladium-catalyzed three-component coupling of aryl iodides, sulfur dioxide, and hydrazines to deliver aryll N-aminosulfonamides is described, and the reaction tolerates significant variation of both the aRYl iodide and Hydrazine coupling partners.
Journal ArticleDOI
The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry
TL;DR: Sulfur dioxide surrogates have been used in a wide range of applications in chemistry, including traditional reactions in which the gaseous reagent has been replaced with a surrogate, and also new transformations for which no Gaseous reaction is known as discussed by the authors.
Journal ArticleDOI
Highly efficient and functional-group-tolerant catalysts for the palladium-catalyzed coupling of aryl chlorides with thiols.
TL;DR: The cross-coupling reaction of aryl chlorides with aliphatic and aromatic thiols catalyzed by palladium complexes of the strongly binding bisphosphine CyPF-tBu ligand is reported, with excellent yields, broad scope and high tolerance of functional groups.
Journal ArticleDOI
DABCO-Bis(sulfur dioxide), DABSO, as a Convenient Source of Sulfur Dioxide for Organic Synthesis: Utility in Sulfonamide and Sulfamide Preparation
TL;DR: The charge-transfer complex generated from the combination of DABCO and sulfur dioxide, DABSO, is a bench-stable colorless solid suitable for use in organic synthesis as a replacement for gaseous sulfur dioxide.