Journal ArticleDOI
Synthetically versatile (trifluoromethanesulfonato)metal amine complexes
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Synthese des complexes M(NH 3 ) 5 (OSO 2 CF 3 ) n+, m(NH 2 CH 3 ) 3 ) (OssO2CF 3 ) 2+, cis-M(en) 2 OssO 2 Cl(OSO2 2 CF3 ) + avec M = metal trivalent as discussed by the authors.Abstract:
Synthese des complexes M(NH 3 ) 5 (OSO 2 CF 3 ) n+ , M(NH 2 CH 3 ) 5 (OSO 2 CF 3 ) 2+ , cis-M(en) 2 (OSO 2 CF 3 ) 2 + et trans-M(en) 2 Cl(OSO 2 CF 3 ) + avec M=metal trivalent. Constantes de vitesse d'aquationread more
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Journal ArticleDOI
Iron(II) Triflate Salts as Convenient Substitutes for Perchlorate Salts: Crystal Structures of [Fe(H2O)6](CF3SO3)2 and Fe(MeCN)4(CF3SO3)2
TL;DR: The most convenient source of anhydrous iron(II) triflate is the acetonitrile solvate isolated from the reaction of finely divided iron metal with triflic acid in acetonihydrate.
Journal ArticleDOI
DNA mismatch binding and antiproliferative activity of rhodium metalloinsertors.
TL;DR: The correlation between binding affinity and targeting of the MMR-deficient cell line suggests that rhodium metalloinsertors exert their selective biological effects on MMR- deficient cells through mismatch binding in vivo.
Journal ArticleDOI
Synthesis and characterization of heteroleptic Cr(diimine)3 3+ complexes
Kylie D. Barker,Kristin A. Barnett,Stuart M. Connell,Jeff W. Glaeser,Amy Jo Wallace,Justin Wildsmith,Brad J. Herbert,John F. Wheeler,Noel A. P. Kane-Maguire +8 more
TL;DR: In this article, a versatile synthetic procedure is described for the synthesis of previously unreported heteroleptic Cr(diimine)3-3+ complexes, which takes advantage of the excellent leaving group characteristics of the trifluoromethanesulfonate (triflate) ligand, CF3SO3.
Journal ArticleDOI
Substitution reactions on cyclometalated Pt(IV) complexes. Associative tuning by fluoro ligands and fluorinated substituents.
TL;DR: The substitution reactions of sulfide by phosphines on Pt(IV) complexes having a cyclometalated imine ligand, two methyl groups in a cis geometrical arrangement, and a halogen and a sulfide as ligands, have been studied as a function of temperature, solvent, and electronic and steric characteristics of the phosphines, sulfides, X, and C-N.
Journal ArticleDOI
Mechanism of the Competition between Phenyl Insertion and Ligand Reductive Elimination on a Hindered Platinum(IV) Cyclometalated Complex
TL;DR: Careful tuning of the reaction conditions has been proved to be essential for the operation of two disjunctive reaction mechanisms occurring on the ortho-metalated platinum compounds [PtIVBr(Ph)2(C...] as mentioned in this paper.