The Crystal Structure of Talc

TLDR: The crystal structure of a sample of talc from Harford County, Maryland, has been deter-mined by least squares refinement from X-ray diffraction photographs as mentioned in this paper, where the layers of the structure have almost monoclinic symmetry but the nearly hexagonal rings of oxygen atoms on the surfaces of the layers, formed by the bases of the silica tetrahedra, are not held in register by interlayer ions as they are in micas but are partly displaced so that the stack of layers forms a triclinic crystal.

Abstract: The crystal structure of a sample of talc from Harford County, Maryland, has been deter- mined by least squares refinement from X-ray diffraction photographs. A triclinic cell with a = 5.293, b = 9.179, c = 9.496A, a = 90'57 ~ = 98-91 ~ y = 90.03, space group cT is adopted. The layers of the structure have almost monoclinic symmetry but the nearly hexagonal rings of oxygen atoms on the surfaces of the layers, formed by the bases of the silica tetrahedra, are not held in register by inter- layer ions as they are in micas but are partly displaced so that the stack of layers forms a triclinic crystal. The hexagons of surface oxygens are distorted by a 3.4 ~ twist of the tetrahedra so that the b axis is 0.2 per cent shorter than in a structure with regular hexagons, and the twist brings the oxygen ions a little closer to the octahedral magnesium ions.