Journal ArticleDOI
The effect of procedural variables on TG, DTG and DTA curves of calcium carbonate
Reads0
Chats0
TLDR
The effect of procedural variables, including sample mass, heating rate, particle size and partial pressure of carbon dioxide, on TG, DTG and DTA curves for the decomposition of A R calcium carbonate and limestone has been studied as discussed by the authors.Abstract:
The effect of procedural variables, including sample mass, heating rate, particle size and partial pressure of carbon dioxide, on TG, DTG and DTA curves for the decomposition of A R calcium carbonate and limestone has been studied Such variables have a marked effect, similar in magnitude for both DTG and DTA The effect of sample mass, or depth of undiluted sample, is shown to be due to an increase in the partial pressure of carbon dioxide within the reacting powder and has been called the bed-depth effect This effect is most pronounced in nitrogen but is much reduced in carbon dioxide Inert diluents have little effect on the TG curves but changing the composition of the inert carrier gas causes variations which are correlated with the thermal conductivity of the gas Water vapour causes a lowering of the DTG and DTA peak temperaturesread more
Citations
More filters
Journal ArticleDOI
What is meant by the term ‘variable activation energy’ when applied in the kinetic analyses of solid state decompositions (crystolysis reactions)?
TL;DR: The proposed introduction of this term, E (variable), is a retrograde step, unlikely to advance science through the development of theory, and its use is not recommended for reasons that are explained.
Journal ArticleDOI
Arrhenius parameters and compensation behaviour in solid-state decompositions
TL;DR: In this paper, the authors examine the reasons for the concurrent changes of Arrhenius frequency factors and activation energies in solid-state decompositions, and three classes can be distinguished.
Journal ArticleDOI
Kinetic analysis of thermogravimetric data obtained under linear temperature programming—a method based on calculations of the temperature integral by interpolation
TL;DR: In this paper, a new technique, called interpolation method, with general application in the kinetic analysis of processes studied by thermogravimetry (TG) under linear temperature programming is developed.
Journal ArticleDOI
Ash properties of some dominant Greek forest species
TL;DR: In this paper, the elemental and chemical wood ash compositions of six dominant Greek fuels were investigated using a variety of techniques, including thermal gravimetric analysis (TG), differential thermal analysis (DTA), atomic absorption spectroscopy (AAS), and X-ray diffraction (XRD).
Journal ArticleDOI
Removal of hydrogen sulfide using crushed oyster shell from pore water to remediate organically enriched coastal marine sediments.
TL;DR: It is concluded that crushed oyster shell can be an effective amendment to remediate organically enriched sediments in eutrophic coastal seas.
References
More filters
Journal ArticleDOI
The effects of sample size and heating rate on the kinetics of the thermal decomposition of CaCO3
P.K. Gallagher,D.W. Johnson +1 more
TL;DR: In this paper, isothermal and dynamic methods were used to study the rate of weight loss of CaCO3 and a pronounced dependence of the activation enthalpy, pre-exponential term, and rate constant upon sample weight and heating rate was observed.
Related Papers (5)
Use of the Langmuir method for kinetic studies of decomposition reactions: calcite (CaCO3)
Dario Beruto,Alan W. Searcy +1 more
Effect of carbon dioxide pressure on the rate of decomposition of calcite (CaCO3)
Taghi Darroudi,Alan W. Searcy +1 more
The effects of sample size and heating rate on the kinetics of the thermal decomposition of CaCO3
P.K. Gallagher,D.W. Johnson +1 more