Journal ArticleDOI
The Mechanism of Oxygenation Reactions Catalyzed by Rhodium(I) Complexes in Solution
B. R. James,E. Ochiai +1 more
TLDR
In this article, the mechanism of oxygenation reactions catalyzed by a rhodium complex which forms a 1:1 molecular oxygen adduct has been elucidated by infrared spectroscopy.Abstract:
The mechanism of oxygenation reactions catalyzed by a rhodium complex which forms a 1:1 molecular oxygen adduct has been elucidated by infrared spectroscopy. Hydrogen abstraction from the substrate...read more
Citations
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Book ChapterDOI
Metal-Catalyzed Oxidations of Organic Compounds in the Liquid Phase: A Mechanistic Approach
TL;DR: In this article, the subject of metal-catalyzed oxidations of organic compounds in the liquid phase, largely within a mechanistic framework, has been discussed and a better understanding of the catalytic action of metal complexes is essential from the view of increasing selectivity and efficiency.
Book ChapterDOI
[66] Phosphoglycerate mutase from yeast, chicken breast muscle, and kidney (2,3-PGA-dependent)
S. Grisolia,J. Carreras +1 more
Journal ArticleDOI
Cycloaddition of group VIII metal-dioxygen complexes to electrophilic olefins
R. A. Sheldon,J. A. Van Doorn +1 more
TL;DR: The dioxygen complexes (Ph 3 P) 2 MO 2 (M Pd, Pt) readily add to electrophilic olefins, such as 1,1-dicyano-olefins as mentioned in this paper, at room temperature, to give cyclic peroxy-adducts in high yield.
Journal ArticleDOI
Homogeneous hydrogenation of unsaturated compounds catalyzed by Pd complexes: I. Scope and effect of variables
E.W. Stern,P.K. Maples +1 more
TL;DR: In this paper, the scope of activity and selectivity in hydrogenations of unsaturated compounds catalyzed by a number of Pd complexes has been explored and the nature of substrates was found to be the most important and to determine the relative effect of other variables.
Journal ArticleDOI
Polyoxoanion-supported, atomically dispersed transition metals: The catalytic oxidation of cyclohexene with dioxygen by the catalyst precursors 6(n-C4H9)4N95Na36(1,5-COD)IraP2W15Nb3O629, 6(n-C4H9)4N95Na36(1,5-COD)RhaP2W15Nb3O629, and 6(n-C4H9)4N94.5Na2.56(C6H6)RuaP2W15Nb3O629
TL;DR: The polyoxoanion-supported iridium(I) complex showed the highest activity of this group with a turnover frequency of 2.9 h −1 at 38°C in CH 2 Cl 2 (540 total turnovers), which is 100-fold greater than its parent iridium compound, [(1,5-COD)IrCl] 2.
References
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Journal ArticleDOI
Rhodium(I) promoted oxygenation of terminal olefins to methyl ketones by molecular oxygen
C. Dudley,G. Read +1 more
Journal ArticleDOI
Analysis of the ESR Spectrum of a Rhodium (II) Complex
Brian R. James,Ei-Ichiro Ochiai +1 more
TL;DR: The ESR spectra of definite Rh(II) species have so far been claimed for Rh in ZnWO3 2, [Rh S4C4(CN)4] as mentioned in this paper.