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The Thermal and the Photolytic Decomposition of 1-Phenyldiazoethane
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This article is published in Journal of Organic Chemistry.The article was published on 1964-05-01. It has received 34 citations till now. The article focuses on the topics: Decomposition.read more
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The Wolff Rearrangement of α-Diazo Carbonyl Compounds
Herbert Meier,Klaus-Peter Zeller +1 more
TL;DR: The readily accessible α-diazo carbonyl compounds are distinguished by their high reactivity, which opens up a variety of preparative applications under modified conditions as mentioned in this paper, and Wolff rearrangements of these compounds, induced thermally, photochemically or catalytically, afford ketenes.
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The 1,2 hydrogen shift: a common vehicle for the disappearance of evanescent molecular species
TL;DR: In this paper, the 1.2 hydrogen shift in carbenes, nitrenes, and vinylidenes was studied and the key role of this isomerization in these unstable intermediates in organic reactions was elucidated.
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Die Wolff‐Umlagerung von α‐Diazocarbonyl‐Verbindungen
Herbert Meier,Klaus-Peter Zeller +1 more
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The wolff rearrangement
TL;DR: The Wolff rearrangement as mentioned in this paper was proposed to solve the problem of synthesizing synthetic reactions competing with the Wolff re-arrangement, and it has been successfully applied in a variety of applications.
Journal ArticleDOI
Über die Valenzisomerie von Diazoverbindungen und Diazirinen
Erika Voigt,Herbert Meier +1 more
TL;DR: In this paper, the first examples of photochromic valence isomerism between diazo compounds and diazirines are presented, and the theoretical routes of their isomerization by ring closure and ring opening, or by elimination and readdition of nitrogen, respectively, are discussed.