Journal ArticleDOI
The vibrational spectra and molecular structure of hexa-1,2-diene-5-yne (propargylallene)
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TLDR
In this paper, the infrared spectra of hexa-1,2-diene-5-yne (propargylallene, HC�C-CH 2 -CHCCH 2 ) were obtained for the vapour and liquid states and for a solid (−180°C) in the region 4000-200 cm −1.About:
This article is published in Journal of Molecular Structure.The article was published on 1978-01-01. It has received 10 citations till now. The article focuses on the topics: Dihedral angle.read more
Citations
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The conformation and vibrational spectra of 1,5-hexadiene-3-yne (divinylacetylene) and perchloro-1,5-hexadiene-3-yne (perchlorodivinylacetylene)
TL;DR: In this article, the spectral properties of 1,5-hexadiene-S-yne and perchlorodivinylacetylene were investigated in the presence of various states of aggregation.
Journal ArticleDOI
The Preparation of the Last Remaining Acyclic Isomers of Benzene
Helmut Maurer,Henning Hopf +1 more
TL;DR: The three acyclic isomers of benzene, 2,3-hexadien-5-yne, 3-methyl-1,2-pentadien 4-yne and 1,2,3,4-hexatetraene, have been prepared by simple routes from readily available starting materials as discussed by the authors.
Journal ArticleDOI
Vibrational spectra, ab initio calculations and vibrational assignments of 3-butyn-1-ol
TL;DR: In this paper, the conformational enthalpy difference between three low energy conformers, HC CCH 2 CH 2 OH, gg, ag, and ag aa, was calculated at MP2 and B3LYP levels with a variety of basis sets.
Journal ArticleDOI
Conformation and vibrational spectra of 1,5-hexadiyne (bipropargyl) and 1,5-hexadiyne-1,6-d2
TL;DR: In this article, the infrared spectra of 1,5-hexadiyne (bipropargyl) and 1,6-d 2 as vapours, liquids, as solutes in various solvents and as crystalline solids at low temperatures and at high pressures have been recorded Raman spectra were obtained for the liquids, including semiquantitative polarization measurements, and for the low temperature crystals.
Journal ArticleDOI
Organic and Organometallic Derivatives of Propargylallene: Syntheses, Structures, Reactivity and Rearrangements
TL;DR: Propargylallenes offer the varied reactivity patterns of two different multiple bond linkages either separately or in concert as discussed by the authors, and their syntheses, structures, rearrangement mechanisms and synthetic utility are reviewed, together with their behaviour when treated with transition-metal reagents such as gold(I), silver, platinum metals or metal carbonyls.
References
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Journal ArticleDOI
Thermische Isomerisierungen, III. Acyclische C6H6-Isomere
TL;DR: In this article, a cyclic C6H6-isomerization of propargylallene (4) to 2-ethynylbuta-1.3-diene (8) was shown to be accompanied by a degenerate valence isomerisation process.
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A low temperature Raman cell: solid spectra of the v1 vibrations of the group IV tetrachlorides
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Photoelectron spectra of open chain C6H6 isomers
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Infra-red spectra, vibrational assignments, and force constants of some monohalogeno diacetylenes, including force constants of some halogeno cyanoacetylenes
TL;DR: In this paper, the infra-red spectra of the monohalogeno diacetylenes HCC-C-B-I and C-C -C-I (X = Cl, Br and I) have been recorded in the gaseous phase and in solution in the region 4000-280 cm−1.
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