Journal ArticleDOI
Thermal isomerization of 1-methylcyclopentadiene
TLDR
The isomerization of 1-methyldicyelopentadiene (III) to 8 methyldicylopentadene (IV) at 145° takes place only by an intramolecular mechanism as discussed by the authors.Abstract:
1.
The isomerization of 1-methyldicyelopentadiene (III) to 8-methyldicyclopentadiene (IV) at 145° takes place only by an intramolecular mechanism.
2.
Depending on the reaction conditions, the diene synthesis can go by two different mechanisms: one-step and two-step.read more
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Reference EntryDOI
The Retro–Diels–Alder Reaction Part I. C ? C Dienophiles
TL;DR: A comprehensive review of the literature on retro Diels-Alder reactions can be found in this article, with a focus on expelling C-C dienophiles, i.e. those reactions that generate a new carbon-carbon double or triple bond in the dienophile.
Journal ArticleDOI
Thermally Crosslinked Functionalized Polydicyclopentadiene with a High Tg and Tunable Surface Energy
TL;DR: The first example of a polymer derived from a carboxyl-functionalized dicyclopentadiene monomer and its subsequent thermal crosslinking and its highest glass-transition temperature is reported, allowing for the facile manipulation of the surface chemistry through alteration of the embedded functional group.
Journal ArticleDOI
ROMP of acetoxy-substituted dicyclopentadiene to a linear polymer with a high Tg
Laijiang Gong,Kun Liu,Encai Ou,Feng Xu,Yanbing Lu,Zhao Wang,Tao Gao,Zhongkui Yang,Weijian Xu +8 more
TL;DR: A polydicyclopentadiene derivative was obtained via ring-opening metathesis polymerization (ROMP) of AcO-DCPD using the Grubbs 1st generation catalyst as discussed by the authors.
Journal ArticleDOI
A Single-Atom Upgrade to Polydicyclopentadiene
Benjamin Godwin,Monir Hosseini Anvari,Tina Olfatbakhsh,Mahshid Mahbod,Abbas S. Milani,Gino A. DiLabio,Jeremy E. Wulff +6 more
TL;DR: In this article , a ketone-functionalized derivative of polydicyclopentadiene is described, which establishes an unprecedented network of vinyl C-H-O hydrogen bonds within the polymer.
References
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Journal ArticleDOI
Some general characteristic properties of substituted cyclopentadienes
TL;DR: In this article, it was shown that the structure of the substituted cyclopentadiene (or the composition of the isomer mixtures) depends mainly on the character of the substituent and not on the method of synthesis.
Journal ArticleDOI
The Pentalenyl Dianion
Journal ArticleDOI
The rearrangement of 4,5,6,7-tetrachloro-3a,4,7,7a-tetrahydro-4,7-methanoiden-8-one☆
Peter Yates,P. Eaton +1 more
TL;DR: In this article, the pathway of the isomerization reaction is interpreted in terms of views recently advanced by Woodward and Katz, which are corroborated by the observation that XV undergoes photoisomerization to give a cage compound (XXXI).
Journal ArticleDOI
Rearrangements of oxo-dicyclopentadienes
TL;DR: In this paper, it was shown that the ratio of cyclopentadiene to cis-3a,7a-dihydroindene (X) decreases in the order 1-ketone > photo-isomer > 8 -ketone.
Journal ArticleDOI
Über das Iso‐dicyclopentadien und das Dehydro‐iso‐dicyclopentadien
TL;DR: Eine Synthese fur das bisher unbekannte Iso-dicyclopentadien (VII) and ein Weg zu dem um zwei H-Atome armeren Dehydro-iso-dicycle-modal (XI) werden angegeben as discussed by the authors.