Journal ArticleDOI
Titanium-induced reductive coupling of carbonyls to olefins
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This article is published in Journal of Organic Chemistry.The article was published on 1978-08-01. It has received 269 citations till now. The article focuses on the topics: Coupling (electronics) & McMurry reaction.read more
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Methods of Reactivity Umpolung
TL;DR: There are six principal methods of umpolung: 1 2n-oxidation, heteroatom exchange and modification, homologation and its reversal, the cyclopropane “trick”, use of acetylenes, and redox reactions; under certain circumstances none of these techniques is necessary in cases where direct umpoline is possible.
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Methoden der Reaktivitätsumpolung
TL;DR: The Umpolung der Reaktivitat wurde als nutzliches heuristisches Prinzip, als Einteilungsschema und als Leitfaden zum Auffinden strategischer Bindungen erkannt (Synthon-, Transform-and Retrosynthesebetrachtungen nach Corey) as mentioned in this paper.
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Single electron transfer in radical ion and radical-mediated organic, materials and polymer synthesis.
TL;DR: The mechanisms and the applications in organic synthesis, materials, supramolecular, and polymer synthesis of most organic reactions mediated by single electron transfer are discussed, even though both biology and radical chemistry rely extensively on one-electron transfer processes.
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Modern methods for the radical deoxygenation of alcohols
TL;DR: In this article, the authors propose the generation of an intermediaire radicalaire par transfert d'electron, which is based on Desoxygenation photolytique.