Journal ArticleDOI
Single electron transfer in radical ion and radical-mediated organic, materials and polymer synthesis.
Reads0
Chats0
TLDR
The mechanisms and the applications in organic synthesis, materials, supramolecular, and polymer synthesis of most organic reactions mediated by single electron transfer are discussed, even though both biology and radical chemistry rely extensively on one-electron transfer processes.Abstract:
The article discusses the mechanisms and the applications in organic synthesis, materials, supramolecular, and polymer synthesis of most organic reactions mediated by single electron transfer. Each reaction or class of reactions will be discussed by starting with the original discovery publication, followed by a summary of all or most review articles published in the field, and a discussion of the mechanism(s) and of the most important methodologic and synthetic developments since the most recent review was published. The mechanisms of most organic reactions are considered to proceed by two-electron transfer pathways, even though both biology and radical chemistry rely extensively on one-electron transfer processes. Radicals generated by homolytic cleavage at high temperature were traditionally employed in the industrial production of polymers and to a lesser extent in the synthesis of organic molecules.read more
Citations
More filters
Journal ArticleDOI
Oxidative C-H/C-H Coupling Reactions between Two (Hetero)arenes.
TL;DR: This review provides a comprehensive overview of the fundamentals and applications of transition metal-mediated/catalyzed oxidative C-H/C-H coupling reactions between two (hetero)arenes.
Journal ArticleDOI
Surface-Initiated Controlled Radical Polymerization: State-of-the-Art, Opportunities, and Challenges in Surface and Interface Engineering with Polymer Brushes
Justin Orazio Zoppe,Nariye Cavusoglu Ataman,Piotr Mocny,Jian Wang,John Moraes,Harm-Anton Klok +5 more
TL;DR: The generation of polymer brushes by surface-initiated controlled radical polymerization (SI-CRP) techniques has become a powerful approach to tailor the chemical and physical properties of interfaces and has given rise to great advances in surface and interface engineering as mentioned in this paper.
Journal ArticleDOI
Modern Electrochemical Aspects for the Synthesis of Value-Added Organic Products.
Sabine Möhle,Michael Zirbes,Eduardo Rodrigo,Tile Gieshoff,Anton Wiebe,Anton Wiebe,Siegfried R. Waldvogel,Siegfried R. Waldvogel +7 more
TL;DR: This Review surveys many of the recent seminal important developments which will determine the future of this dynamic emerging field of organic synthesis.
Journal ArticleDOI
Radicals: Reactive Intermediates with Translational Potential
TL;DR: This Perspective illustrates the defining characteristics of free radical chemistry, beginning with its rich and storied history, and studies from the laboratory are discussed along with recent developments emanating from others in this burgeoning area.
Journal ArticleDOI
Organocatalysis in Inert C–H Bond Functionalization
Yan Qin,Lihui Zhu,Sanzhong Luo +2 more
TL;DR: This review provides a comprehensive summary of organocatalysis in inert C-H bond functionalization over the past two decades as well as those activated benzylic, allylic, and C- H bonds alpha to the heteroatom such as nitrogen and oxygen.
References
More filters
Book
Advanced Inorganic Chemistry
TL;DR: Cotton and Wilkinson's Advanced Inorganic Chemistry (AIC) as discussed by the authors is one of the most widely used inorganic chemistry books and has been used for more than a quarter century.
Journal ArticleDOI
Electron transfers in chemistry and biology
Rudolph A. Marcus,Norman Sutin +1 more
TL;DR: In this paper, the electron transfer reactions between ions and molecules in solution have been the subject of considerable experimental study during the past three decades, including charge transfer, photoelectric emission spectra, chemiluminescent electron transfer, and electron transfer through frozen media.
Journal ArticleDOI
Controlled/"living" radical polymerization. atom transfer radical polymerization in the presence of transition-metal complexes
Journal ArticleDOI
Synthesis of Conjugated Polymers for Organic Solar Cell Applications
TL;DR: Fluorene-Based Copolymers ContainingPhosphorescent Complexes and Carbazole-Based Conjugated Polymers R5.1.3.
Related Papers (5)
Single-Electron Transfer and Single-Electron Transfer Degenerative Chain Transfer Living Radical Polymerization
Brad M. Rosen,Virgil Percec +1 more