Journal ArticleDOI
Unsaturated polyesters, III. Polyester from maleic anhydride and 1,4‐butylene glycol
TLDR
The polyesterification reaction of maleic anhydride and 1,4-butylene glycol was carried out, using p-toluensulphonic acid as catalyst The resulting material was characterized by IR and H1-NMR spectroscopy, end group analysis, and gel permeation chromatography as mentioned in this paper.Abstract:
The polyesterification reaction of maleic anhydride and 1,4-butylene glycol was carried out, using p-toluensulphonic acid as catalyst The resulting material was characterized by IR and H1-NMR spectroscopy, end group analysis, and gel permeation chromatography It is shown that there is a relationship between maleate to fumarate isomerization and steric interaction among condensed groups on the one hand and the tendency of the reacting system to crosslink or gelread more
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Rigid, thermosetting liquid molding resins from renewable resources. I. Synthesis and polymerization of soy oil monoglyceride maleates
TL;DR: In this article, a rigid thermoset polymers were prepared from radical copolymerization of the soybean oil monoglyceride maleates with styrene in order to obtain rigid, thermopolymerized polymers.
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Soybean and castor oil based monomers: Synthesis and copolymerization with styrene
TL;DR: In this article, castor oil was alcoholyzed with both aliphatic alcohols, such as glycerol and pentaerythritol, and an aromatic alcohol, bisphenol A propoxylate.
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Unsaturated, biobased polyesters and their cross-linking via radical copolymerization
TL;DR: In this paper, unsaturated polyesters derived from isosorbide, maleic anhydride and succinic acid were synthesized and characterized using FT-IR spectroscopy and by measurements of the soluble part of the cured coatings.
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Biobased multiblock copolymers: Synthesis, properties and shape memory behavior of poly(hexamethylene 2,5-furandicarboxylate)-b-poly(ethylene glycol)
TL;DR: In this paper, a series of multiblock copolymers poly(hexamethylene 2,5-furandicarboxylate)-b-poly(ethylene glycol) (PHFEGs) were synthesized from available biobased FDCA, 1,6-hexanediol (HD), and poly(ethylenes glycol), by a two-step melt polycondensation method.
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Synthesis and electrospun fiber mats of low Tg poly(propylene fumerate‐co‐propylene maleate)
TL;DR: In this article, a similar crosslinkable polymer system, poly(propylene fumerate)-co-(propylene maleate) (PPFcPM), derived from maleic anhydride (MA) and 1,2-propylene diol (PD), was examined.