Journal ArticleDOI
Unusual structural and magnetic resonance properties of dicyclopentadienylhexacarbonyldichromium
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This article is published in Journal of the American Chemical Society.The article was published on 1974-02-01. It has received 151 citations till now.read more
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Coordination chemistry of polychalcogen anions and transition metal carbonyls
TL;DR: In this paper, the chemistry of heavy polychalcogenides as ligands to transition metal centers is discussed, which involves the coordination of poly-chogenide anions to metal carbonyls.
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The Crystal and Molecular Structure of Bis(cyclopentadienyldicarbonylchromium) (CrCr)
TL;DR: In this article, the crystal structure of bis(cyclopentadienyldicarbonyl-chromium) has been determined by x-ray diffraction, and two independent molecules per unit cell located at the inversion centers at O,O,O and O, 1/2, O. The Cp Cr Cr angles in the two molecules are 165.0° and 158.7°, respectively.
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Metalmetal multiple bonds
TL;DR: The synthesis and chemistry of Cp 2 Mo 2 (CO) 4 (I) a coplex containing a reaction Mo�Mo triple bond, are described in this paper, where the formation of I in refluxing xylene is shown to occur via odd-electron intermediates from homolysis of the MoMo bond in the Cp2 Mo 2(CO) 6 precursor.
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Photogeneration of dinuclear metal carbonyls containing a metal-metal triple bond
TL;DR: In this article, the authors formulated the triple-bonded complexes as metal-metal triple bonded complexes, which can be generated from the corresponding (η5-C5H5)M(CO)3]2 and (γ-5C(in5)(CH3)5m(CO)-2]2 complexes by either irradiation at 25° or by heating.