Journal ArticleDOI
Vinyl-chloride polymerization to 2 500 atm
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TLDR
In this article, the authors investigated the effect of the change in phase ratio during the polymerization of vinyl-chloride polyvinylide (VVC) at 50°C and up to 2 500 atm.About:
This article is published in Polymer.The article was published on 1969-01-01. It has received 10 citations till now. The article focuses on the topics: Bulk polymerization & Polymerization.read more
Citations
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Journal ArticleDOI
Role of slow phase separation in assessing the equilibrium phase behaviour of PC-PMMA blends
TL;DR: In this article, it was shown that the phase separation that occurs on heating above the glass transition is not a result of a lower critical solution temperature (LCST) just above Tg but stems from an extremely slow rate of phase separation from the trapped nonequilibrium state.
Book ChapterDOI
Thermal Degradation of PVC
T. Hjertberg,E. M. Sörvik +1 more
TL;DR: In this article, the authors summarized the research related to thermal degradation of unstabilised polyvinyl chloride (PVC) at conditions characteristic of processing, i.e., low oxygen levels and temperatures up to 250°C.
Journal ArticleDOI
High Pressure Kinetic Investigations in Organic and Macromolecular Chemistry
TL;DR: In this article, high pressure kinetics appears to be a valuable tool in investigating the mechanism of specific organic reactions, such as pericyclic, Mentshutkin, cage, and polymerization reactions.
Journal ArticleDOI
Polymerizations at High Pressures
TL;DR: The role of pressure in the control of natural phenomena has been investigated in this paper, with the goal of understanding how to control and use pressure effectively so that we may use it effectively.
Journal ArticleDOI
Hochdruck‐kinetische Untersuchungen in der Organischen und Makromolekularen Chemie
TL;DR: Kinetische Untersuchungen bei hohen Drucken sind ein sehr nutzliches Verfahren zur Aufklarung des Mechanismus einer Vielfalt organischer Reaktionen as mentioned in this paper.
References
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Journal ArticleDOI
The Activated Complex in Chemical Reactions
TL;DR: In this paper, the probability of the activated state is calculated using ordinary statistical mechanics, and the probability multiplied by the rate of decomposition gives the specific rate of reaction, and necessary conditions for general statistical treatment to reduce to the usual kinetic treatment are given.
Journal ArticleDOI
Some applications of the transition state method to the calculation of reaction velocities, especially in solution
Related Papers (5)
Vinyl chloride studies. Part 1.—Kinetics of polymerization of vinyl chloride in chlorobenzene solution
G. S. Park,D. G. Smith +1 more