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Viscosity and local liquid structure in dimethyl sulfoxide-water mixtures

Steven A. Schichman, +1 more
- 01 Jan 1971 - 
- Vol. 75, Iss: 1, pp 98-102
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This article is published in The Journal of Physical Chemistry.The article was published on 1971-01-01. It has received 140 citations till now. The article focuses on the topics: Viscosity & Dimethyl sulfoxide.

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Water dynamics in water/DMSO binary mixtures.

TL;DR: The dynamics of dimethyl sulfoxide/water solutions with a wide range of water concentrations are studied using polarization selective infrared pump-probe experiments, two-dimensional infrared (2D IR) vibrational echo spectroscopy, optical heterodyne detected optical Kerr effect (OHD-OKE) experiments, and IR absorption spectra.
Journal ArticleDOI

Temperature-dependent perturbation of phospholipid bilayers by dimethylsulfoxide.

TL;DR: Investigation of sulfoxide vibrations indicate that DMSO is not hydrogen bonded to the alcohol moiety of octanol, and therefore the interaction between D MSO and octanol is most likely due to a hydrophobic association.
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Water in Biological and Chemical Processes: From Structure and Dynamics to Function

TL;DR: Water in Biology: Dynamical View and Function: 6. Biological water 7. Explicit role of water in biological functions 8. Hydration of proteins 9. Can we understand protein hydration layer: lessons from computer simulations as mentioned in this paper.
Journal ArticleDOI

Efficient multiple-solvent suppression for the study of the interactions of organic solvents with biomolecules

TL;DR: Application of the modification of the excitation sculpting sequence to the peptide Sandostatin® dissolved in H2O and DMSO is demonstrated and allows rapid and sensitive detection of weak interactions between organic solvents or small molecules and biomolecules.
Journal ArticleDOI

Solution viscosity effects on the heterogeneous electron transfer kinetics of ferrocenemethanol in dimethyl sulfoxide-water mixtures

TL;DR: The electrochemical kinetics for the oxidation of ferrocenemethanol (FcCH2OH) over the whole composition range of dimethyl sulfoxide (DMSO)-water solutions of different viscosities ( ) containing 500 mM (CH3)4NClO4 (TMAP) at a Pt microelectrode was studied using scanning electrochemical microscopy (SECM) as mentioned in this paper.
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