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Journal ArticleDOI

Wood Panel Adhesives from Low Molecular Mass Lignin and Tannin without Synthetic Resins

TLDR
In this paper, mixed interior wood panel tannin adhesive formulations were developed in which lignin was in considerable proportion, 50%, of the wood panel binder, and in which no 'fortification' with synthetic resins, such as isocyanates or phenol-formaldehyde resins as used in the past, was necessary to obtain results satisfying relevant standards.
Abstract
Mixed interior wood panel tannin adhesive formulations were developed in which lignin was in considerable proportion, 50%, of the wood panel binder, and in which no 'fortification' with synthetic resins, such as isocyanates or phenol-formaldehyde resins as used in the past, was necessary to obtain results satisfying relevant standards. A low molecular mass lignin obtained industrially by formic acid/acetic acid pulping of wheat straw was used. Environment-friendly, non-toxic polymeric materials of natural origin constitute up to 94% of the total panel binder. The wood panel itself is constituted of 99.5% natural materials, the balance 0.5% being composed of glyoxal, a non-toxic and non-volatile aldehyde, and of hexamine already accepted as a non-formaldehyde-yielding compound when in presence of very reactive chemical species such as a flavonoid tannin. Particleboards and two types of plywoods were shown to pass the relevant interior standards with such adhesive formulations. Moreover, the much cheaper no...

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Journal ArticleDOI

Valorization of bark for chemicals and materials: A review

TL;DR: In this article, the technical routes and technologies on the valorization of tree barks for chemicals and materials are reviewed, including direct utilization of bark for wooden panels, and extraction for extractives (mainly tannin) and their application in resins and foam materials, as well as conversion of bark via thermochemical technologies, mainly phenolysis, direct liquefaction in alcohols and pyrolysis.
Journal ArticleDOI

Bio-Based Adhesives and Evaluation for Wood Composites Application.

TL;DR: This article reviews the recent research published over the last few decades on the synthesis of bio-adhesives derived from such renewable resources as lignin, starch, and plant proteins and discusses techniques commonly used for evaluating the petroleum-based wood adhesives in terms of mechanical properties and penetration behavior.
Journal ArticleDOI

Tannins: Prospectives and Actual Industrial Applications

TL;DR: The article presents historical applications of tannins, such as leather, or traditional medicine, and more recent applications, as well as future applications which are being developed at present and that promise to have an industrial impact in the future.
Journal ArticleDOI

Wood Composites and Their Polymer Binders.

TL;DR: This review presents first, rather succinctly, what are the important points to look out for when preparing good wood Composites, the main types of wood composites manufactured industrially, and the mainly oil-derived wood composite adhesives and binders that dominate and have been dominating this industry.
Journal ArticleDOI

Gluten Protein Adhesives for Wood Panels

TL;DR: In this article, the results of the 30/70 pMDI/hydroxymethylated lignin adhesive formulation were tried at progressively shorter pressing times yielding internal bond strength results acceptable for relevant interior grade standards at industrially significant pressing times.
References
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Book

Functional analysis

Walter Rudin
BookDOI

Wood: chemistry, ultrastructure, reactions.

TL;DR: The anatomy and chemistry of wood are described in detail, and with extensive reference to the literature, under the following headings: Introduction; Structure and ultrastructure; Chemical composition and analysis of wood; Cellulose; Polyoses (hemicelluloses); Lignin; Extractives; Distribution of the components within the wood cell wall; Constituents of bark; Reactions in acidic medium; reactions in alkaline medium; Influence of temperature; Degradation by light and ionizing rays; Microbial and enzymatic degradation; Aging and fossilization; Pul
Journal ArticleDOI

Recent developments in eco-efficient bio-based adhesives for wood bonding: opportunities and issues

TL;DR: In this article, a review of recent developments and trends in the field of eco-efficient bio-based adhesives is presented, with an example of cashew nut shell oil modified by a new and inexpensive method of ozonolysis to yield an adhesive.
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