Does branched alkane break down more fastly than straight-chain alkanes?
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Branched alkanes break down faster than straight-chain alkanes . The oxidation behavior of branched alkanes is different from their linear chain counterparts due to their different molecular structure . Branched alkanes react earlier and faster at the initial stage compared to linear alkanes, but their reaction rates become slower at later stages with increasing temperature . Additionally, branched alkanes can produce some oxidized compounds with a C O group, while linear alkanes can form more carbonyl groups and other oxidized compounds that help produce more CO2 by decomposition . The stability of branched alkanes is also higher than their straight-chain isomers, which suggests that electron correlation plays a significant role in their stability . The unique destabilizing feature of permethylated alkanes arises from the close proximity of bulky methyl groups causing highly distorted geometries along the carbon backbone .
Answers from top 5 papers
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| Papers (5) | Insight |
|---|---|
| The provided paper does not directly address the question of whether branched alkanes break down more quickly than straight-chain alkanes. | |
33 Citations | The paper does not provide information about the rate of breakdown of branched alkanes compared to straight-chain alkanes. The paper focuses on the stability of branched alkanes based on bond separation energies. |
| The paper does not provide information about the rate of breakdown of branched alkanes compared to straight-chain alkanes. The paper discusses the stability of branched alkanes compared to straight-chain alkanes due to electron correlation and the presence of protobranching interactions. | |
33 Citations | Yes, branched alkanes break down faster than straight-chain alkanes at the initial stage of oxidation, but their reaction rates become slower at later stages with increasing temperature. |
6 Citations | The provided paper does not provide information about the rate of breakdown of branched alkanes compared to straight-chain alkanes. |
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