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How to extract platinum and palladium from catalytic converter? 

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The present work provides a simple and rapid method for the separation of platinum (IV) from real samples of the autocatalytic converter.
Therefore, the method is an efficient, effective and highly selective approach to extract Pd(II) and recover metal palladium.
The absence of deactivation for the Pt/γ-Al2O3 catalyst may be explained by slower formation of coke precursors on platinum compared to palladium.
With EDTA and multiple extractions, the method is satisfactory for the determination of palladium in the presence of other platinum-group elements and many other cations.
As large amounts of platinum and palladium can be extracted quantitatively as readily as small amounts, the proposed scheme is applicable to a wide range of platiniferous materials, particularly to those with extremely high Pt + Pd to Rh + Ir ratios.
Preliminary extraction data achieved with single metal ion solutions pointed out to a possible separation of platinum(IV) from palladium(II).
It overcomes the problems that palladium has leached badly and recovery difficultly in conventional homogeneous palladium catalyst field, and have a broad foreground of catalyst applications.
The method is satisfactorily applied to the determination of palladium in some palladium catalysts.