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What are the chemical reactions involved in the production of SiO2 particles through vaporization, oxidation, and condensation? 


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The production of SiO2 particles through vaporization, oxidation, and condensation involves various chemical reactions. In oxygen-rich circumstellar environments, SiO molecules react with OH radicals and H2O, affecting the efficiency of dust formation . Additionally, the reaction between SiO(g) and CO(g) on SiC particles at elevated temperatures leads to the formation of brown condensate, consisting of Si spheres embedded in a SiO2 matrix . Furthermore, a cost-efficient method for producing SiO2 particles involves depositing SiO2 onto core particles by decreasing the pH value of an aqueous reaction composition over time . Another method includes preparing a dispersion liquid of composite oxide particles with a specific molar ratio of MOx/SiO2 to obtain particles with an average diameter in a specific range .

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The production of SiO2 particles involves vaporization of SiO(g) and CO(g), oxidation reactions, and condensation resulting in Si spheres embedded in a SiO2 matrix.
Patent
11 Dec 2013
6 Citations
Not addressed in the paper.
The reactions involve SiO oxidation by OH and H2O, leading to SiO2 formation. Si2O2 reacts faster with OH than SiO, while SiO + H2O forms molecular complexes due to high activation energies.

Related Questions

How to remove SiO2 powder in duct?5 answersTo remove SiO2 powder in a duct, various methods can be employed based on the provided research contexts. One approach involves using pressurized air to dislodge powder particles adhering to the interior surfaces of the duct. Another method includes a system utilizing pressurized air to separate unnecessary powdery matter from powder, preventing scattering and reducing vibration and noise. Additionally, an acid material removing device and method on the SiO2 surface can be implemented, which involves setting a bar-shaped copy board along the inner wall of a deacidifying furnace to remove the material. These methods collectively offer efficient ways to clean and remove SiO2 powder from ducts, ensuring effective maintenance and operation of powder transfer systems.
What is the chemical vapor condensation method(By evaporating/vaporizing and condensing/cooling) used for manufacturing nano Si in SiO2 matrix particles?4 answersThe chemical vapor condensation method used for manufacturing nano Si in SiO2 matrix particles involves a process where a chemical etchant is locally delivered at the nanoscale in the vapor phase by capillary condensation, forming a meniscus at the nanoparticle/substrate interface. This method does not require functionalization of the nanoparticles and relies on the aqueous nature of the solution and the wettability properties of the surfaces involved, making it applicable to various material and chemical combinations. Additionally, the synthesis of graphitized Si nanoparticles can be achieved through a chemical vapor deposition approach using ethanol as the carbon feedstock, which aids in the formation of graphene layers coating the Si nanoparticles at lower temperatures compared to traditional methods.
Method for manufacturing nano Si in SiO2 matix particles using vapor phase synthesis from Si and SiO2 raw materials?4 answersVapor phase synthesis of nano Si in SiO2 matrix particles can be achieved through various methods. One approach involves utilizing a CO2 laser pyrolysis reactor with an elongated reaction zone, which enhances the production of silicon nanoparticles from SiH4 gas, influencing their size distribution. Another method includes the green synthesis of luminescent Si/SiO2 nanoparticles through the reduction of 3-aminopropyltriethoxysilane, showcasing an average size of 12.8±0.2nm. Additionally, a manufacturing method for SiO2 nanoparticles involves preparing a reaction mixture solution by adding tetraethylorthosilicate (TEOS) and ammonia to a water particle dispersion, followed by decomposing water particles to obtain SiO2 nanoparticles, all while avoiding toxic solvents and surfactants. These diverse techniques demonstrate the versatility in producing nano Si in SiO2 matrix particles through vapor phase synthesis.
Effect of SiO2 nano particles on bacteria?4 answersSiO2 nanoparticles have been found to have an inhibitory effect on the growth of bacteria. In one study, SiO2 nanoparticles were shown to inhibit the growth of Bacillus coagulans, a beneficial gut bacteria used as a probiotic. Another study demonstrated that SiO2 nanoparticles incorporated into polyvinyl chloride improved the antimicrobial properties of medical devices, including blood bags. Additionally, SiO2 nanoparticles functionalized with silver nanoparticles exhibited excellent antibacterial activity against Escherichia coli bacteria. Furthermore, ZnO@SiO2 nanoparticles based on rice husk were effective in removing Escherichia coli bacteria from water. Overall, these findings suggest that SiO2 nanoparticles can have both inhibitory and antibacterial effects on various types of bacteria.
Is SiO2 acidic?3 answersSiO2 particles have been studied in multiple papers to determine their acidic properties. The fused SiO2 particles were found to have a higher intrinsic pKa2 value compared to fumed SiO2 particles, indicating a higher acidity level. Additionally, the acidic polishing slurry containing colloidal silica abrasive and fluoride salt showed a higher polishing selectivity for removing silica compared to silicon nitride. The acidity evaluations of TiO2-SiO2-Al2O3 catalysts revealed that the acid amount of TiO2-SiO2-Al2O3 was nearly double that of SiO2-Al2O3, indicating a higher acidity level. Furthermore, investigations comparing the acidic properties of single oxide TiO2, SiO2, Al2O3, and their binary and ternary oxides showed that TiO2-SiO2-Al2O3 had the highest acid amount and activity in alkylation and dehydration reactions. The study of TiO2-SiO2 catalysts with different Ti/Si mole ratios also confirmed the presence of acid centers in SiO2. Therefore, based on these findings, SiO2 can be considered acidic.
What is the potentiel redox of SiO2/Si ?5 answersThe potential redox of SiO2/Si is influenced by various factors such as the Si oxidation states, surface chemistry, and growth conditions. The Si oxidation states can be adjusted by controlling the ratio of metalloid ions/metalloid atoms in the starting mixture, which affects the reactivity of the resulting solid. The distribution of oxidation states at SiO2/Si interfaces can be determined using surface-sensitive spectroscopy, providing insights into the structural models for the interface. Additionally, the presence of Si/SiO2 quantum dots can alter cellular redox homeostasis, leading to changes in glutathione distribution and protein redox status. These findings highlight the importance of understanding the redox properties of SiO2/Si systems in various applications, including catalysis and biomedical research.

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