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What are the specific chemical reactions that occur between the carboxyl group and Omid in hydrogel pva/am/mba/pei/aps/amps?

Self-healing hydrogels

Aqueous solution

Concentration effect

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The specific chemical reactions that occur between the carboxyl group and Omid in the PVA/AM/MBA/PEI/APS/AMPS hydrogel involve crosslinking reactions. In the synthesis process, carboxyl groups from various components like carboxymethylcellulose (CMC) and fumaric acid (FA) react with hydroxyl groups of poly(vinyl alcohol) (PVA) and other compounds through ester formation, leading to crosslinking. Additionally, in aqueous solutions of borates, PVA hydrogels exhibit reversible changes in tensile forces in response to pH and glucose concentrations, indicating dynamic interactions possibly involving carboxyl groups. These crosslinking reactions play a crucial role in enhancing the mechanical properties and stability of the hydrogel, as observed in studies on PVA/PVP composite hydrogels.

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Journal Article•DOI Mechanochemical Reaction of Poly(Vinyl Alcohol) Gels Due to Cooperative Effects of Crosslinks – Respondences to pH and Glucose Masakatsu Yonese, Kazuhiko Baba, Masatoshi Kondo, Hiroshi Kishimoto - Show less +3 more 01 Feb 1992-Chemistry Letters 1 Citations	Not addressed in the paper.
Journal Article•DOI Fumaric acid cross-linked carboxymethylcellulose/poly(vinyl alcohol) hydrogels Merve Dilaver, Kadir Yurdakoç - Show less +1 more 04 Feb 2016-Polymer Bulletin 24 Citations	Not addressed in the paper.
Book Chapter•DOI Reactions of the carboxyl group F. D. Gunstone 01 Jan 1996 4 Citations	Not addressed in the paper.
Open access•Journal Article Molecular dynamics simulation on mechanical properties of PVP / PVA Wang Yan-e 01 Jan 2014-Journal of Medical Biomechanics 1 Citations	Not addressed in the paper.

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