Showing papers on "Triphenyl phosphate published in 1991"
TL;DR: Triphenyl phosphate and a brominated phosphate were compared as flame retardant additives for polycarbonate/ABS blends as mentioned in this paper, and the concentration of the flame retardants was varied from 6 to 14%.
Abstract: Triphenyl phosphate and a brominated phosphate were compared as flame retardant additives for polycarbonate/ABS blends. The concentration of the flame retardant was varied from 6 to 14% and the polycarbonate/ABS ratio was varied from 3/1 to 1/1. A commercial polycarbonate/ABS blend is 3/1 with about 14% triphenyl phosphate for a UL-94 V-0/5V rating. Reducing the polycarbonate or the flame retardant level gives products which do not pass UL-94 V-0/5V. Compositions containing the brominated phosphate with UL-94 V-0/5V ratings include use of 6% flame retardant or 14% flame retardant with polymer ratios down to 1/1. Cone calorimetry data show significantly longer time to ignition, lower total heat release and lower peak heat release rate for the brominated phosphate-containing resin. Mechanical properties are also given.
20 citations
Patent•
15 May 1991
TL;DR: A flame retardant composition for use in flexible urethane foams, which contains about 5 to 95 % of tris(monochloroalkyl, dichloroenalkyl or mixtures thereof) phosphate and the remainder is a phenyl phosphate ester which is an alkylated triphenyl phosphate having an approximate average formula (RxArO)3PO wherein x ranges from 1 to 2, each R is individually selected from the group consisting of hydrogen, C1-C4 alkyl and Ar is phenyl.
Abstract: A flame retardant composition, for use in flexible urethane foams, which contains about 5 to 95 % of tris(monochloroalkyl, dichloroalkyl or mixtures thereof) phosphate and the remainder is a phenyl phosphate ester which is an alkylated triphenyl phosphate having an approximate average formula (RxArO)3PO wherein x ranges from 1 to 2, each R is individually selected from the group consisting of hydrogen, C1-C4 alkyl and Ar is phenyl. Flexible urethane foam compositions containing 8 to 14 parts per 100 parts polyol of this composition have sufficient flame retardant properties to meet the Cal 117 test standard.
16 citations
Patent•
07 Jun 1991
TL;DR: In this article, an expandable, powder coating composition of a thermoplastic resin containing a hydroxyl group-containing polymer, a cross-linking agent containing a polyisocyanate compound which is capable crosslinking the resin, and a blowing agent consisting of a mixture of a solid plasticizer such as triphenyl phosphate and a liquid plasticiser such as dioctyl phthalate is described.
Abstract: An expandable, powder coating composition is disclosed which includes (a) a thermoplastic resin containing a hydroxyl group-containing polymer, (b) a cross-linking agent containing a polyisocyanate compound which is capable crosslinking the thermoplastic resin, (c) a blowing agent, and (d) a mixture of a solid plasticizer such as triphenyl phosphate and a liquid plasticizer such as dioctyl phthalate.
6 citations
Patent•
07 Nov 1991
TL;DR: In this article, the authors proposed a method to prepare the title compsn. excellent in the flame retardance by compounding a polyphenylene ether resin, a polystyrene resin, polyric ester compd., and a specific carbon fiber, each in a specified amt.
Abstract: PURPOSE:To prepare the title compsn. excellent in the flame retardance by compounding a polyphenylene ether resin, a polystyrene resin, a phosphric ester compd., and a specific carbon fiber, each in a specified amt. CONSTITUTION:100 pts.wt. compsn. comprising 20-97 pts.wt. polyphenylene ether resin (e.g. a polyphenylene ether), 0-70 pts.wt. polystyrene resin (e.g. a polystyrene), and 3-30 pts.wt. phosphoric ester compd. (e.g. triphenyl phosphate) is compounded with 4-45 pts.wt. carbon fiber having a density of 1.9g/cm or higher.
3 citations
Journal Article•
2 citations
Patent•
18 Jul 1991
TL;DR: A thermoplastic aromatic polyimide composition obtained by blending (A) 100 pts.wt., preferably 0.30-0.70 reduced viscosity with (B) 0.1-2 pts.
Abstract: PURPOSE:To obtain a thermoplastic aromatic polyimide composition improved in thermal stability and viscosity stability in melt molding by blending an aromatic polyimide with a specific amount of a specified organic phosphoric acid ester. CONSTITUTION:A thermoplastic aromatic polyimide composition obtained by blending (A) 100 pts.wt. thermoplastic aromatic polyimide, prepared by polymerizing an aromatic tetracarboxylic acid component with an aromatic diamine component and an aromatic dicarboxylic acid component and imidating the resultant polymer and having preferably 0.25-1.0, preferably 0.30-0.70 reduced viscosity with (B) 0.002-5 pts.wt., preferably 0.1-2 pts.wt. organic phosphoric acid ester, e.g. triphenyl phosphate or tris(4-tert-butylphenyl) phosphate, expressed by the formula (X is H, hydroxyl group, 1-8C aliphatic hydrocarbon group, 6-18C aromatic hydrocarbon group or 1-8C alkoxy).
2 citations
Patent•
11 Apr 1991
TL;DR: In this paper, the authors proposed a method to prepare a flame-retardant cured product having excellent wear resistance and high surface hardness by reacting a monomer or oligomer component contg. with a flame retardant in the presence of a polymn.
Abstract: PURPOSE:To prepare a flame-retardant cured product having excellent wear resistance and high surface hardness by reacting a monomer or oligomer contg. a diallyl compd. with a flame retardant in the presence of a polymn. initiator. CONSTITUTION:A flame-retardant cured product is obtd. by reacting a monomer or oligomer component contg. a diallyl compd. or a mixture of these components with a compsn. contg. a flame retardant in the presence of a polymn. initiator. Examples of the diallyl compd. are monomers and oligomers of a bisallyl carbonate of an aliph., alicyclic, or arom. dihydric alcohol, and the mixtures of these compds. The usable flame retardants include brominated flame retardants (e.g. tetrabromobisphenol), inorg. flame retardants (e.g. antimony trichloride), organophosphorus flame retardants (e.g. triphenyl phosphate), and inorg. phosphorus flame retardants (e.g. red phosphorus).
1 citations
Patent•
15 Jul 1991
TL;DR: In this article, a flame retarding resin composition is provided having excellent thermal stability and good impact resistance, the composition consists of a thermoplastic resin selected from the group of high impact polystyrene, polyethylene terephthalate, polybutylene polycarbonate and polymer blend and contains a polybrominated triphenyl phosphate ester.
Abstract: A flame retarding resin composition is provided having excellent thermal stability and good impact resistance. The composition consists of a thermoplastic resin selected from the group of high impact polystyrene, polyethylene terephthalate, polybutylene terephthalate, acrylonitrile-butadiene-styrene polycarbonate and polymer blend and contains a polybrominated triphenyl phosphate ester having a molar ratio of bromine to phosphorus of from 6 to 9, and less than 5% antimony oxide.
1 citations
Patent•
15 May 1991
TL;DR: A flame retardant composition for use in flexible urethane foams, which contains about 5 to 95 % of tris(monochloroalkyl, dichloroenalkyl or mixtures thereof) phosphate and the remainder is a phenyl phosphate ester which is an alkylated triphenyl phosphate having an approximate average formula (RxArO)3PO wherein x ranges from 1 to 2, each R is individually selected from the group consisting of hydrogen, C1-C4 alkyl and Ar is phenyl as discussed by the authors.
Abstract: A flame retardant composition, for use in flexible urethane foams, which contains about 5 to 95 % of tris(monochloroalkyl, dichloroalkyl or mixtures thereof) phosphate and the remainder is a phenyl phosphate ester which is an alkylated triphenyl phosphate having an approximate average formula (RxArO)3PO wherein x ranges from 1 to 2, each R is individually selected from the group consisting of hydrogen, C1-C4 alkyl and Ar is phenyl. Flexible urethane foam compositions containing 8 to 14 parts per 100 parts polyol of this composition have sufficient flame retardant properties to meet the Cal 117 test standard.