Andrea Daolio

TL;DR: Decamethonium diiodide is reported to perform the chemo- and regio-selective encapsulation of para-dihalobenzenes via competitive formation of halogen bonded cocrystals starting from solutions containing also ortho and meta isomers.

TL;DR: In this paper , experimental findings are reported proving that the sulfur atom of benzisothiazol-3(2H)-one derivatives have a remarkable tendency to form short and directional chalcogen bonds on the extension of the covalent N-S bond and, to a lesser extent, of the C-S. The results suggest that the electrophility of sulfur may play a role also at earlier stages than the reactive ones.

TL;DR: In this paper , combined experimental and theoretical results show that the occurrence of σ-hole interactions in catalytic systems extends to MTO, and four crystalline adducts between MTO and aliphatic and heteroaromatic bases are obtained, and their X-ray analyses display short Re-N/O contacts opposite to both O-Re and C-Re covalent bonds with geometries consistent with σhole interactions.

TL;DR: In this paper , a wheel-shaped ligand with geminal rotating fluorine atoms was shown to have the best mobility of correlated dipolar rotors at 2 K, with practically null activation energy (Ea = 17 cal/mol).

TL;DR: In this article , five structures bearing the N,N,N-trimethylammonium unit have been investigated to address the ability of the N+-CH3 unit to function as a tetrel bond donor site.