The amendment of two agricultural soils with two biochars derived from the slow pyrolysis of papermill waste was assessed in a glasshouse study. Characterisation of both biochars revealed high surface area (115 m2 g−1) and zones of calcium mineral agglomeration. The biochars differed slightly in their liming values (33% and 29%), and carbon content (50% and 52%). Molar H/C ratios of 0.3 in the biochars suggested aromatic stability. At application rates of 10 t ha−1 in a ferrosol both biochars significantly increased pH, CEC, exchangeable Ca and total C, while in a calcarosol both biochars increased C while biochar 2 also increased exchangeable K. Biochars reduced Al availability (ca. 2 cmol (+) kg−1 to <0.1 cmol (+) kg−1) in the ferrosol. The analysis of biomass production revealed a range of responses, due to both biochar characteristics and soil type. Both biochars significantly increased N uptake in wheat grown in fertiliser amended ferrosol. Concomitant increase in biomass production (250% times that of control) therefore suggested improved fertiliser use efficiency. Likewise, biochar amendment significantly increased biomass in soybean and radish in the ferrosol with fertiliser. The calcarosol amended with fertiliser and biochar however gave varied crop responses: Increased soybean biomass, but reduced wheat and radish biomass. No significant effects of biochar were shown in the absence of fertiliser for wheat and soybean, while radish biomass increased significantly. Earthworms showed preference for biochar-amended ferrosol over control soils with no significant difference recorded for the calcarosol. The results from this work demonstrate that the agronomic benefits of papermill biochars have to be verified for different soil types and crops.

Effects of biochar from slow pyrolysis of papermill waste on agronomic performance and soil fertility

Role of organic amendments on enhanced bioremediation of heavy metal(loid) contaminated soils

A review on application of flocculants in wastewater treatment

This century has witnessed remarkable achievements in green technology in material science through the development of natural fiber reinforced composites. The development of high-performance engineering products made from natural resources is increasing worldwide day by day. There is increasing interest in materials demonstrating efficient use of renewable resources. Nowadays, more than ever, companies are faced with opportunities and choices in material innovations. Due to the challenges of petroleum-based products and the need to find renewable solutions, more and more companies are looking at natural fiber composite materials. The primary driving forces for new bio-composite materials are the cost of natural fibers (currently priced at one-third of the cost of glass fiber or less), weight reduction (these fibers are half the weight of glass fiber), recycling (natural fiber composites are easier to recycle) and the desire for green products. This Review provides an overview of natural fiber reinfocred composites focusing on natural fiber types and sources, processing methods, modification of fibers, matrices (petrochemical and renewable), and their mechanical performance. It also focuses on future research, recent developments and applications and concludes with key issues that need to be resolved. This article critically summarizes the essential findings of the mostly readily utilized reinforced natural fibers in polymeric composite materials and their performance from 2000 to 2013.

https://onlinelibrary.wiley.com/doi/pdf/10.1002/mame.201300008

Progress Report on Natural Fiber Reinforced Composites

Composites have been found to be the most promising and discerning material available in this century. Presently, composites reinforced with fibers of synthetic or natural materials are gaining more importance as demands for lightweight materials with high strength for specific applications are growing in the market. Fiber-reinforced polymer composite offers not only high strength to weight ratio, but also reveals exceptional properties such as high durability; stiffness; damping property; flexural strength; and resistance to corrosion, wear, impact, and fire. These wide ranges of diverse features have led composite materials to find applications in mechanical, construction, aerospace, automobile, biomedical, marine, and many other manufacturing industries. Performance of composite materials predominantly depends on their constituent elements and manufacturing techniques, therefore, functional properties of various fibers available worldwide, their classifications, and the manufacturing techniques used to fabricate the composite materials need to be studied in order to figure out the optimized characteristic of the material for the desired application. An overview of a diverse range of fibers, their properties, functionality, classification, and various fiber composite manufacturing techniques is presented to discover the optimized fiber-reinforced composite material for significant applications. Their exceptional performance in the numerous fields of applications have made fiber-reinforced composite materials a promising alternative over solitary metals or alloys.

/pdf/fiber-reinforced-polymer-composites-manufacturing-properties-f0ipegmttq.pdf

Fiber-Reinforced Polymer Composites: Manufacturing, Properties, and Applications.

Waste management from pulp and paper production in the European Union

A methodology to study flocculation processes and floc properties using a non-imaging scanning laser microscope is presented in this paper. This methodology allows us to study floc stability and resistance to shear forces, re-flocculation tendency and reversibility of the flocs. Furthermore, optimal dosage of any polymer and the associated flocculation mechanism can be determined. In order to illustrate the technique, some examples applied to flocculation in papermaking are described. Although in this paper all the examples have been applied to papermaking, the developed methodology can be used in any process in which flocculation phenomena is involved.

Flocculation Monitoring: Focused Beam Reflectance Measurement as a Measurement Tool

Nanocellulose materials have emerged as a new family of nanomaterials of great interest. That is due to their environmental advantages, including their production from renewable resources, their biodegradability, biocompatibility and their high potential availability. The production processes and the properties of CNF, CNC and BC (aspect ratio, mechanical strength, elastic modulus and thermal stability, high surface area, low density and oxygen permeability, etc) will be described in detailed. Their potential applications in relation to their properties will be mentioned in general terms as an introduction to the specific applications described in the other sections (e.g. papermaking, composites, packaging, electronic devices, coatings, biomedicine, automotive, etc). The description could be focussed on the traditional and emerging trends for their production, their characterization and the quality demanded for the final applications.

Nanocellulose for Industrial Use: Cellulose Nanofibers (CNF), Cellulose Nanocrystals (CNC), and Bacterial Cellulose (BC)

Nanocelluloses (NC) increase mechanical and barrier paper properties allowing the use of paper in applications actually covered by other materials. Despite the exponential increase of information, NC have not been fully implemented in papermaking yet, due to the challenges of using NC. This paper provides a review of the main new findings and emerging possibilities in this field by focusing mainly on: (i) Decoupling the effects of NC on wet-end and paper properties by using synergies with retention aids, chemical modification, or filler preflocculation; (ii) challenges and solutions related to the incorporation of NC in the pulp suspension and its effects on barrier properties; and (iii) characterization needs of NC at an industrial scale. The paper also includes the market perspectives. It is concluded that to solve these challenges specific solutions are required for each paper product and process, being the wet-end optimization the key to decouple NC effects on drainage and paper properties. Furthermore, the effect of NC on recyclability must also be taken into account to reach a compromise solution. This review helps readers find upscale options for using NC in papermaking and identify further research needs within this field.

https://www.mdpi.com/1420-3049/25/3/526/pdf

Industrial Application of Nanocelluloses in Papermaking: A Review of Challenges, Technical Solutions, and Market Perspectives.

Nanocelluloses (NCs) are bio-based nano-structurated products that open up new solutions for natural material sciences. Although a high number of papers have described their production, properties, and potential applications in multiple industrial sectors, no review to date has focused on their possible use in cementitious composites, which is the aim of this review. It describes how they could be applied in the manufacturing process as a raw material or an additive. NCs improve mechanical properties (internal bonding strength, modulus of elasticity (MOE), and modulus of rupture (MOR)), alter the rheology of the cement paste, and affect the physical properties of cements/cementitious composites. Additionally, the interactions between NCs and the other components of the fiber cement matrix are analyzed. The final result depends on many factors, such as the NC type, the dosage addition mode, the dispersion, the matrix type, and the curing process. However, all of these factors have not been studied in full so far. This review has also identified a number of unexplored areas of great potential for future research in relation to NC applications for fiber-reinforced cement composites, which will include their use as a surface treatment agent, an anionic flocculant, or an additive for wastewater treatment. Although NCs remain expensive, the market perspective is very promising.

https://www.mdpi.com/2073-4360/11/3/518/pdf

Angeles Blanco

Papers

Waste management from pulp and paper production in the European Union

Flocculation Monitoring: Focused Beam Reflectance Measurement as a Measurement Tool

Nanocellulose for Industrial Use: Cellulose Nanofibers (CNF), Cellulose Nanocrystals (CNC), and Bacterial Cellulose (BC)

Industrial Application of Nanocelluloses in Papermaking: A Review of Challenges, Technical Solutions, and Market Perspectives.

Nanocelluloses: Natural-Based Materials for Fiber-Reinforced Cement Composites. A Critical Review