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Anil Kumar Vardhaman
Researcher at Indian Institute of Chemical Technology
Publications - 20
Citations - 786
Anil Kumar Vardhaman is an academic researcher from Indian Institute of Chemical Technology. The author has contributed to research in topics: Electron transfer & Hydrogen atom abstraction. The author has an hindex of 12, co-authored 20 publications receiving 675 citations. Previous affiliations of Anil Kumar Vardhaman include Ewha Womans University & Indian Institute of Technology Guwahati.
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Visible light assisted photocatalytic hydrogen generation and organic dye degradation by CdS–metal oxide hybrids in presence of graphene oxide
Ziyauddin Khan,Tridip Ranjan Chetia,Anil Kumar Vardhaman,Dipankar Barpuzary,Chivukula V. Sastri,Mohammad Qureshi +5 more
TL;DR: In this paper, single step hydrothermal synthesis of CdS/Oxide (Oxide = ZnO, Al2O3) was demonstrated and examined their photocatalytic activity in presence of graphene oxide (GO).
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A Manganese(V)–Oxo Complex: Synthesis by Dioxygen Activation and Enhancement of Its Oxidizing Power by Binding Scandium Ion
Seungwoo Hong,Yong Min Lee,Muniyandi Sankaralingam,Anil Kumar Vardhaman,Young Jun Park,Kyung Bin Cho,Takashi Ogura,Ritimukta Sarangi,Shunichi Fukuzumi,Wonwoo Nam +9 more
TL;DR: This study reports the first example of tuning the second coordination sphere of high-valent metal-oxo species by binding a redox-inactive metal ion at the supporting ligand site, thereby modulating their electron-transfer properties as well as their reactivities in oxidation reactions.
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Long-Range Electron Transfer Triggers Mechanistic Differences between Iron(IV)-Oxo and Iron(IV)-Imido Oxidants
Suresh Kumar,Abayomi S. Faponle,Prasenjit Barman,Anil Kumar Vardhaman,Chivukula V. Sastri,Devesh Kumar,Sam P. de Visser +6 more
TL;DR: It is shown here that iron( IV)-tosylimido complex is much more reactive with sulfides than the corresponding iron(IV)-oxo complex; however, the reverse trend is obtained for hydrogen atom abstraction reactions.
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Comparison of the Reactivity of Nonheme Iron(IV)–Oxo versus Iron(IV)–Imido Complexes: Which is the Better Oxidant?†
Anil Kumar Vardhaman,Prasenjit Barman,Suresh Kumar,Chivukula V. Sastri,Devesh Kumar,Sam P. de Visser +5 more
TL;DR: The iron( IV)-imido variant reacts with sulfides five times faster than iron(IV)-oxo, whereas the reverse trend is observed for hydrogen atom abstraction.
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Nonheme ferric hydroperoxo intermediates are efficient oxidants of bromide oxidation.
TL;DR: This work presents the first combined experimental and computational study that gives evidence of the electrophilic reactivity of a nonheme iron(III)-hydroperoxo species.