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Baokun Qiao
Researcher at Henan University
Publications - 31
Citations - 1432
Baokun Qiao is an academic researcher from Henan University. The author has contributed to research in topics: Enantioselective synthesis & Catalysis. The author has an hindex of 20, co-authored 30 publications receiving 915 citations. Previous affiliations of Baokun Qiao include Rutgers University.
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Journal ArticleDOI
Conjugate Addition-Enantioselective Protonation of N-Aryl Glycines to α-Branched 2-Vinylazaarenes via Cooperative Photoredox and Asymmetric Catalysis.
Yanli Yin,Yanli Yin,Yating Dai,Hongshao Jia,Jiangtao Li,Liwei Bu,Baokun Qiao,Xiaowei Zhao,Zhiyong Jiang +8 more
TL;DR: An enantioselective protonation strategy has been successfully applied to the synthesis of chiral α-tertiary azaarenes and an application of this methodology to a two-step synthesis of the enantiomerically pure medicinal compound pheniramine is presented.
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Catalytic Enantioselective Addition of Prochiral Radicals to Vinylpyridines.
Kangning Cao,Kangning Cao,Siu Min Tan,Richmond Lee,Songwei Yang,Hongshao Jia,Xiaowei Zhao,Baokun Qiao,Zhiyong Jiang,Zhiyong Jiang +9 more
TL;DR: The first enantioselective addition of prochiral radicals to vinylpyridines under cooperative photoredox and asymmetric catalysis mediated by visible light is described and valuable chiral γ-secondary/tertiary hydroxyl- and amino-substituted pyridine derivatives were obtained.
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Formal enantioconvergent substitution of alkyl halides via catalytic asymmetric photoredox radical coupling.
TL;DR: It is reported that visible light-driven catalytic asymmetric photoredox radical coupling can act as a complementary and generic strategy for the enantioconvergent formal substitution of alkyl haldies with readily available and bench-stable organic molecules.
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Organocatalytic Enantioselective Addition of α-Aminoalkyl Radicals to Isoquinolines.
TL;DR: An enantioselective Minisci-type addition of α-amino acid-derived redox-active esters (RAEs) to isoquinolines has been developed, providing a range of valuable α-isoquinoline-substituted chiral secondary amines in high yields with good to excellent enantiOSElectivities.
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All-Carbon Quaternary Stereocenters α to Azaarenes via Radical-Based Asymmetric Olefin Difunctionalization.
Yanli Yin,Yanli Yin,Yanli Yin,Yunqiang Li,Théo P. Gonçalves,Qiangqiang Zhan,Guanghui Wang,Xiaowei Zhao,Baokun Qiao,Kuo-Wei Huang,Zhiyong Jiang,Zhiyong Jiang +11 more
TL;DR: A radical-based asymmetric olefin difunctionalization strategy for rapidly forging all-carbon quaternary stereocenters α to diverse azaarenes is reported, achieving high enantio- and diastereo-selectivities for these asymmetric [3 + 2] cycloadditions.