The carrier collection efficiency (ηc) and energy conversion efficiency (ηe) of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives. Composite films of poly(2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylene vinylene) (MEH-PPV) and fullerenes exhibit ηc of about 29 percent of electrons per photon and ηe of about 2.9 percent, efficiencies that are better by more than two orders of magnitude than those that have been achieved with devices made with pure MEH-PPV. The efficient charge separation results from photoinduced electron transfer from the MEH-PPV (as donor) to C60 (as acceptor); the high collection efficiency results from a bicontinuous network of internal donor-acceptor heterojunctions.

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Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

Energy harvested directly from sunlight offers a desirable approach toward fulfilling, with minimal environmental impact, the need for clean energy. Solar energy is a decentralized and inexhaustible natural resource, with the magnitude of the available solar power striking the earth’s surface at any one instant equal to 130 million 500 MW power plants.1 However, several important goals need to be met to fully utilize solar energy for the global energy demand. First, the means for solar energy conversion, storage, and distribution should be environmentally benign, i.e. protecting ecosystems instead of steadily weakening them. The next important goal is to provide a stable, constant energy flux. Due to the daily and seasonal variability in renewable energy sources such as sunlight, energy harvested from the sun needs to be efficiently converted into chemical fuel that can be stored, transported, and used upon demand. The biggest challenge is whether or not these goals can be met in a costeffective way on the terawatt scale.2

http://pubs.acs.org/doi/pdf/10.1021/cr1002326

Solar Water Splitting Cells

Evidence for photoinduced electron transfer from the excited state of a conducting polymer onto buckminsterfullerene, C(60), is reported. After photo-excitation of the conjugated polymer with light of energy greater than the pi-pi* gap, an electron transfer to the C(60) molecule is initiated. Photoinduced optical absorption studies demonstrate a different excitation spectrum for the composite as compared to the separate components, consistent with photo-excited charge transfer. A photoinduced electron spin resonance signal exhibits signatures of both the conducting polymer cation and the C(60) anion. Because the photoluminescence in the conducting polymer is quenched by interaction with C(60), the data imply that charge transfer from the excited state occurs on a picosecond time scale. The charge-separated state in composite films is metastable at low temperatures.

https://science.sciencemag.org/content/sci/258/5087/1474.full.pdf

Photoinduced electron transfer from a conducting polymer to buckminsterfullerene.

The interest in heterogeneous photocatalysis is intense and increasing, as shown by the number of publications on this theme which regularly appear in this journal, and the fact that over 2000 papers have been published on this topic since 1981. This article is an overview of the field of semiconductor photocatalysis : a brief examination of its roots, achievements and possible future. The semiconductor titanium dioxide (TiO 2 ) features predominantly in past and present work on semiconductor photocatalysis; as a result, in the most of the examples selected in this overview to illustrate various points the semiconductor is TiO 2 .

An overview of semiconductor photocatalysis

Preface Acknowledgements Notation Part I. Overview and Background Topics: 1. Introduction 2. Overview 3. Theoretical background 4. Periodic solids and electron bands 5. Uniform electron gas and simple metals Part II. Density Functional Theory: 6. Density functional theory: foundations 7. The Kohn-Sham ansatz 8. Functionals for exchange and correlation 9. Solving the Kohn-Sham equations Part III. Important Preliminaries on Atoms: 10. Electronic structure of atoms 11. Pseudopotentials Part IV. Determination of Electronic Structure, The Three Basic Methods: 12. Plane waves and grids: basics 13. Plane waves and grids: full calculations 14. Localized orbitals: tight binding 15. Localized orbitals: full calculations 16. Augmented functions: APW, KKR, MTO 17. Augmented functions: linear methods Part V. Predicting Properties of Matter from Electronic Structure - Recent Developments: 18. Quantum molecular dynamics (QMD) 19. Response functions: photons, magnons ... 20. Excitation spectra and optical properties 21. Wannier functions 22. Polarization, localization and Berry's phases 23. Locality and linear scaling O (N) methods 24. Where to find more Appendixes References Index.

Electronic Structure: Basic Theory and Practical Methods

Active, passive, and hybrid mode locking of a monolithic extended‐cavity semiconductor laser with an integrated saturable absorber have been demonstrated. Actively mode locked at a repetition rate of 8.6 GHz, 6.2 ps pulses were measured. Hybrid mode locking resulted in 4.4 ps pulses. The extended‐cavity laser also exhibits self‐starting passive mode locking at a repetition rate of 8.57 GHz with 5.5 ps pulses. A broad spectrum allows wavelength selectivity over a range of 15 nm with little change in the pulse width.

InGaAsP monolithic extended‐cavity lasers with integrated saturable absorbers for active, passive, and hybrid mode locking at 8.6 GHz

The balanced operation of a multiple-quantum-well balanced heterodyne receiver photonic integrated circuit (PIC) is described. Using only SMA-connected 50 Omega commercial electronics, a free-space beam sensitivity of -42.3 dBm at 108 Mb/s and -39.7 dBm at 200 Mb/s for NRZ FSK (frequency-shift keying) reception has been achieved. This represents a 14 dB improvement over any previous heterodyne receiver PIC sensitivity. In addition to providing the multichannel benefits of heterodyne reception, this is also the highest sensitivity yet reported for any OEIC (optoelectronic integrated circuit) receiver. >

Balanced operation of a GaInAs/GaInAsP multiple-quantum-well integrated heterodyne receiver

We describe planar buried heterostructure lasers which have low capacitance (lpF), large bandwidth (19GHz), high power (>20mW/facet) and high temperature operation (100°C). These lasers are very suitable for long-distance, highspeed digital and analogue signal transmission.

High-speed, polyimide-based semi-insulating planar buried heterostructures

We describe the structure and performance characteristics of an InGaAs/InP multiple-quantum-well (MQW) electro-absorption buried-mesa optical modulator The device is fabricated with two metal-organic chemical-vapour-deposition (MOCVD) growth steps, wherein small-area circular (40μm diameter) PIN diodes are buried with Fe-doped semiinsulating (SI) InP regrowth The modulator has a relatively low insertion loss (45 dB) with 25% modulation depth and very high modulation bandwith (53 GHz) operating at 162μm wavelength

High-frequency InGaAs/InP multiple-quantum-well buried-mesa electroabsorption optical modulator

GaInAs/InP planar buried heterostructure (PBH) lasers with semi-insulating blocking layers were grown in an `all? atmospheric OMVPE system. These layers had current thresholds as low as 35 mA and differential quantum efficiencies of ?16% at a wavelength of 1.64 ?m. The maximum power output was 80 mW pulsed and 8mWCW.

Barry Miller

Papers

InGaAsP monolithic extended‐cavity lasers with integrated saturable absorbers for active, passive, and hybrid mode locking at 8.6 GHz

Balanced operation of a GaInAs/GaInAsP multiple-quantum-well integrated heterodyne receiver

High-speed, polyimide-based semi-insulating planar buried heterostructures

High-frequency InGaAs/InP multiple-quantum-well buried-mesa electroabsorption optical modulator

Planar buried heterostructure InP/GaInAs lasers grown entirely by OMVPE