J. Appl. Cryst.の発刊に際して

There are numerous potential applications for superconducting tapes based on YBa(2)Cu(3)O(7-x) (YBCO) films coated onto metallic substrates. A long-established goal of more than 15 years has been to understand the magnetic-flux pinning mechanisms that allow films to maintain high current densities out to high magnetic fields. In fact, films carry one to two orders of magnitude higher current densities than any other form of the material. For this reason, the idea of further improving pinning has received little attention. Now that commercialization of YBCO-tape conductors is much closer, an important goal for both better performance and lower fabrication costs is to achieve enhanced pinning in a practical way. In this work, we demonstrate a simple and industrially scaleable route that yields a 1.5-5-fold improvement in the in-magnetic-field current densities of conductors that are already of high quality.

Strongly enhanced current densities in superconducting coated conductors of YBa2Cu3O7-x + BaZrO3

Magnetic flux can penetrate a type-II superconductor in the form of Abrikosov vortices (also called flux lines, flux tubes, or fluxons) each carrying a quantum of magnetic flux phi 0=h/2e. These tiny vortices of supercurrent tend to arrange themselves in a triangular flux-line lattice (FLL), which is more or less perturbed by material inhomogeneities that pin the flux lines, and in high-Tc superconductors (HTSCs) also by thermal fluctuations. Many properties of the FLL are well described by the phenomenological Ginzburg-Landau theory or by the electromagnetic London theory, which treats the vortex core as a singularity. In Nb alloys and HTSCs the FLL is very soft mainly because of the large magnetic penetration depth lambda . The shear modulus of the FLL is c66~1/ lambda 2, and the tilt modulus c44(k)~(1+k2 lambda 2)-1 is dispersive and becomes very small for short distortion wavelengths 2 pi /k<< lambda . This softness is enhanced further by the pronounced anisotropy and layered structure of HTSCs, which strongly increases the penetration depth for currents along the c axis of these (nearly uniaxial) crystals and may even cause a decoupling of two-dimensional vortex lattices in the Cu-O layers. Thermal fluctuations and softening may `melt` the FLL and cause thermally activated depinning of the flux lines or ofthe two-dimensional `pancake vortices` in the layers. Various phase transitions are predicted for the FLL in layered HTSCs. Although large pinning forces and high critical currents have been achieved, the small depinning energy so far prevents the application of HTSCs as conductors at high temperatures except in cases when the applied current and the surrounding magnetic field are small.

https://iopscience.iop.org/article/10.1088/0034-4885/58/11/003/pdf

The flux-line lattice in superconductors

Magnetic flux can penetrate a type-II superconductor in form of Abrikosov vortices. These tend to arrange in a triangular flux-line lattice (FLL) which is more or less perturbed by material inhomogeneities that pin the flux lines, and in high-$T_c$ supercon- ductors (HTSC's) also by thermal fluctuations. Many properties of the FLL are well described by the phenomenological Ginzburg-Landau theory or by the electromagnetic London theory, which treats the vortex core as a singularity. In Nb alloys and HTSC's the FLL is very soft mainly because of the large magnetic penetration depth: The shear modulus of the FLL is thus small and the tilt modulus is dispersive and becomes very small for short distortion wavelength. This softness of the FLL is enhanced further by the pronounced anisotropy and layered structure of HTSC's, which strongly increases the penetration depth for currents along the c-axis of these uniaxial crystals and may even cause a decoupling of two-dimensional vortex lattices in the Cu-O layers. Thermal fluctuations and softening may melt the FLL and cause thermally activated depinning of the flux lines or of the 2D pancake vortices in the layers. Various phase transitions are predicted for the FLL in layered HTSC's. The linear and nonlinear magnetic response of HTSC's gives rise to interesting effects which strongly depend on the geometry of the experiment.

The Flux-Line Lattice in Superconductors

Major food adulteration and contamination events seem to occur with some regularity, such as the widely publicised adulteration of milk products with melamine and the recent microbial contamination of vegetables across Europe for example. With globalisation and rapid distribution systems, these can have international impacts with far-reaching and sometimes lethal consequences. These events, though potentially global in the modern era, are in fact far from contemporary, and deliberate adulteration of food products is probably as old as the food processing and production systems themselves. This review first introduces some background into these practices, both historically and contemporary, before introducing a range of the technologies currently available for the detection of food adulteration and contamination. These methods include the vibrational spectroscopies: near-infrared, mid-infrared, Raman; NMR spectroscopy, as well as a range of mass spectrometry (MS) techniques, amongst others. This subject area is particularly relevant at this time, as it not only concerns the continuous engagement with food adulterers, but also more recent issues such as food security, bioterrorism and climate change. It is hoped that this introductory overview acts as a springboard for researchers in science, technology, engineering, and industry, in this era of systems-level thinking and interdisciplinary approaches to new and contemporary problems.

Fingerprinting food: current technologies for the detection of food adulteration and contamination

The aim of this work is to investigate the mechanisms controlling the current-carrying capability of ${\mathrm{YBa}}_{2}{\mathrm{Cu}}_{3}{\mathrm{O}}_{7\mathrm{\ensuremath{-}}\mathrm{\ensuremath{\delta}}}$ thin films. A comparison between the magnetic properties of a film with intrinsic grain-boundary defects and two films crossed by columnar defects with different densities is presented. Such properties have been studied by means of ac susceptibility measurements, resistivity measurements, and structural characterizations. The Clem and Sanchez model [Phys. Rev. B 50, 9355 (1994)] is used to extract critical current values from the susceptibility data. In the virgin film, correlated grain-boundary defects were created among islands with homogeneous size, by means of the appropriate modifications in the growth process. Columnar defects were produced through 0.25-GeV Au-ion irradiation. The central issue concerns the investigation of the plateaulike features characterizing the log-log field dependence of the critical current density, the analysis of the ${J}_{c}$ temperature dependence, and of the irreversibility line. An analytical expression of ${J}_{c}$ vs B is given in order to compare the main issues with the experimental data. This model suggests that the intergrain pinning dominates in the high-current/low-temperature regime through a network of frustrated Josephson junctions, while the intragrain pinning is effective near the irreversibility line.

Control of the critical current density in YBa 2 Cu 3 O 7 − δ films by means of intergrain and intragrain correlated defects

Superconductor‐normal metal‐superconductor (SNS) Josephson junctions consisting of Y‐Ba‐Cu‐O/Au/Nb film‐layered structure have been fabricated using epitaxial Y‐Ba‐Cu‐O films. SNS junctions with a‐b plane orientated Y‐Ba‐Cu‐O films exhibit the Josephson effect, while the junctions with c‐axis orientated Y‐Ba‐Cu‐O films have no Josephson current. Moreover, a‐b plane orientated junctions show anisotropic Fraunhofer patterns in the magnetic field dependence of the critical current according to the direction of film orientations. These anisotropic behaviors reveal that the proximity effect is strongly affected by the anisotropic coherence length and the magnetic penetration depth of Y‐Ba‐Cu‐O films.

Anisotropic Josephson junctions of Y‐Ba‐Cu‐O/Au/Nb film sandwiches

Er:YAG laser treatments on dentine surface: micro-Raman spectroscopy and SEM analysis.

A wavelet multi-component decomposition algorithm is proposed for processing data from micro-Raman spectroscopy (μ-RS) of biological tissue. The μ-RS has been recently recognized as a promising tool for the biopsy test and in vivo diagnosis of degenerative human tissue pathologies, due to the high chemical and structural information contents of this spectroscopic technique. However, measurements of biological tissues are usually hampered by typically low-level signals and by the presence of noise and background components caused by light diffusion or fluorescence processes. In order to overcome these problems, a numerical method based on discrete wavelet transform is used for the analysis of data from μ-RS measurements performed in vitro on animal (pig and chicken) tissue samples and, in a preliminary form, on human skin and oral tissue biopsy from normal subjects. Visible light μ-RS was performed using a He–Ne laser and a monochromator with a liquid nitrogen cooled charge coupled device equipped with a grating of 1800 grooves mm−1. The validity of the proposed data procedure has been tested on the well-characterized Raman spectra of reference acetylsalicylic acid samples.

Carlo Camerlingo

Papers

Control of the critical current density in YBa 2 Cu 3 O 7 − δ films by means of intergrain and intragrain correlated defects

Anisotropic Josephson junctions of Y‐Ba‐Cu‐O/Au/Nb film sandwiches

Er:YAG laser treatments on dentine surface: micro-Raman spectroscopy and SEM analysis.

Wavelet data processing of micro-Raman spectra of biological samples

Visible micro-Raman spectroscopy for determining glucose content in beverage industry