C
Cesar Mateo
Researcher at Delft University of Technology
Publications - 13
Citations - 1031
Cesar Mateo is an academic researcher from Delft University of Technology. The author has contributed to research in topics: Epoxide hydrolase & Nitrilase. The author has an hindex of 11, co-authored 13 publications receiving 971 citations. Previous affiliations of Cesar Mateo include Autonomous University of Madrid & Centre national de la recherche scientifique.
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Journal ArticleDOI
A new, mild cross-linking methodology to prepare cross-linked enzyme aggregates.
TL;DR: It is proposed that macromolecular cross‐linkers are too large to penetrate the protein active site and react with catalytically essential amino acid residues.
Journal ArticleDOI
Modulation of the enantioselectivity of lipases via controlled immobilization and medium engineering: hydrolytic resolution of mandelic acid esters
Jose M. Palomo,Gloria Fernández-Lorente,Cesar Mateo,Claudia Ortiz,Roberto Fernandez-Lafuente,Jose M. Guisan +5 more
TL;DR: Using different derivatives, it has been possible to obtain both pure enantiomers from the ester or the product, and changes in the E values were obtained in the hydrolysis of methyl mandelate though here always there was a enantiopreference for the S isomer.
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Synthesis of enantiomerically pure (S)-mandelic acid using an oxynitrilase–nitrilase bienzymatic cascade: a nitrilase surprisingly shows nitrile hydratase activity
TL;DR: It was shown, in separate experiments, that the nitrilase hydrolyses ( S )-mandelonitrile into an approx.
Journal ArticleDOI
Solid-phase handling of hydrophobins: immobilized hydrophobins as a new tool to study lipases.
José M. Palomo,María M. Peñas,Gloria Fernandez-Lorente,Cesar Mateo,Antonio G. Pisabarro,Roberto Fernández-Lafuente,Lucía Ramírez,Jose M. Guisan +7 more
TL;DR: The binding of Pleurotus ostreatus hydrophobins to a hydrophilic matrix (agarose) to construct a support for noncovalent immobilization and activation of lipases from Candida antarctica, Humicola lanuginosa, and Pseudomonas flourescens is reported.
Journal ArticleDOI
Nitrile Hydratase Activity of a Recombinant Nitrilase
Bruno C. M. Fernandes,Cesar Mateo,Christoph Kiziak,Andrzej Chmura,Jan Wacker,Fred van Rantwijk,Andreas Stolz,Roger A. Sheldon +7 more
TL;DR: Amide formation increased when the α-substituent was electron-deficient; 2-chloro-2-phenylacetonitrile, for example, afforded 89 % amide, and a similar effect was found for the O-acetyl derivatives.