In this chapter, we will restrict our attention to the ferrites and a few other closely related materials. The great interest in ferrites stems from their unique combination of a spontaneous magnetization and a high electrical resistivity. The observed magnetization results from the difference in the magnetizations of two non-equivalent sub-lattices of the magnetic ions in the crystal structure. Materials of this type should strictly be designated as “ferrimagnetic” and in some respects are more closely related to anti-ferromagnetic substances than they are to ferromagnetics in which the magnetization results from the parallel alignment of all the magnetic moments present. We shall not adhere to this special nomenclature except to emphasize effects, which are due to the existence of the sub-lattices.

Ferromagnetic materials

A new energy paradigm, consisting of greater reliance on renewable energy sources and increased concern for energy effi ciency in the total energy lifecycle, has accelerated research into energy-related technologies. Due to their ubiquity, magnetic materials play an important role in improving the effi ciency and performance of devices in electric power generation, conditioning, conversion, transportation, and other energy-use sectors of the economy. This review focuses on the state-of-the-art hard and soft magnets and magnetocaloric materials, with an emphasis on their optimization for energy applications. Specifi cally, the impact of hard magnets on electric motor and transportation technologies, of soft magnetic materials on electricity generation and conversion technologies, and of magnetocaloric materials for refrigeration technologies, are discussed. The synthesis, characterization, and property evaluation of the materials, with an emphasis on structure‐property relationships, are discussed in the context of their respective markets, as well as their potential impact on energy effi ciency. Finally, considering future bottlenecks in raw materials, options for the recycling of rare-earth intermetallics for hard magnets will be discussed.

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Magnetic materials and devices for the 21st century: Stronger, lighter, and more energy efficient

A review was presented to demonstrate a historical description of the synthesis of light-emitting conjugated polymers for applications in electroluminescent devices. Electroluminescence (EL) was first reported in poly(para-phenylene vinylene) (PPV) in 1990 and researchers continued to make significant efforts to develop conjugated materials as the active units in light-emitting devices (LED) to be used in display applications. Conjugated oligomers were used as luminescent materials and as models for conjugated polymers in the review. Oligomers were used to demonstrate a structure and property relationship to determine a key polymer property or to demonstrate a technique that was to be applied to polymers. The review focused on demonstrating the way polymer structures were made and the way their properties were controlled by intelligent and rational and synthetic design.

Synthesis of Light-Emitting Conjugated Polymers for Applications in Electroluminescent Devices

Hexagonal ferrites: A review of the synthesis, properties and applications of hexaferrite ceramics

Recycling of rare earths: a critical review

A comprehensive and systematic study on Sm(Co/sub bal/Fe/sub v/Cu/sub y/Zr/sub x/)/sub z/ magnets is made to completely understand the effects of composition and processing on their magnetic properties. These studies include the compositions required for the formation of cellular/lamellar microstructure, the effects of compositions (x, y, v, z) and processing (aging temperature and time) on microstructure and magnetic properties, the evolution of microstructure and magnetic properties and the magnetic hardening. All of these effects and results may be summed up as changing microstructure and microchemistry, which leads to a variation of the distribution and amount of Cu at the 1:5 cell boundaries. This becomes the most predominant factor controlling the pinning strength and therefore the coercivity and its temperature dependence.

High temperature 2:17 magnets: relationship of magnetic properties to microstructure and processing

A class of promising permanent-magnet materials with an appreciable high-temperature coercivity of 8.6 kOe at 500 °C is reported. The Sm–Co–Cu–Ti magnets are prepared by arc melting and require a suitable heat treatment. Magnetization measurements as a function of temperature and x-ray diffraction patterns indicate that the samples are two-phase mixtures of 2:17 and 1:5 structures. Depending on heat treatment and composition, some of the magnets exhibit a positive temperature coefficient of coercivity. The promising high-temperature behavior of the coercivity is ascribed to the temperature dependence of the domain-wall energy, which affects the curvature of the walls and the pinning behavior.

/pdf/sm-co-cu-ti-high-temperature-permanent-magnets-2biupupwkt.pdf

Sm–Co–Cu–Ti high-temperature permanent magnets

Sintered Sm2(Co,Fe,Cu,Zr)17 magnets with improved high temperature performance have been obtained by reducing the iron content in the magnet alloys. A record intrinsic coercive force, IHC, of 8.3 kOe at 400 °C was obtained when the iron content was decreased to 7 wt%. At 400–600 °C, 2:17 magnets with low iron content have demonstrated lower irreversible loss of magnetic flux, higher maximum energy product, and lower temperature coefficient of IHC. A temperature coefficient of IHC=−0.12%/°C (20–400 °C) was obtained for the low Fe magnets, compared to −0.23%/°C for commercial 2:17. Reducing iron content increases both Curie temperature and anisotropy field. Therefore, it is anticipated that new 2:17 magnet materials capable of operating at 400 °C or higher temperatures can be developed by reducing or eliminating the iron content and making other adjustments in composition and heat treatment.

Christina H. Chen

Papers

Magnetic materials and devices for the 21st century: Stronger, lighter, and more energy efficient

High temperature 2:17 magnets: relationship of magnetic properties to microstructure and processing

Sm–Co–Cu–Ti high-temperature permanent magnets

Sm2(Co,Fe,Cu,Zr)17 magnets for use at temperature ⩾400 °C

Magnetic Materials and Devices for the 21st Century: Stronger, Lighter, and More Energy Efficient