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Daniel R. Tolentino
Researcher at University of California, San Diego
Publications - 10
Citations - 421
Daniel R. Tolentino is an academic researcher from University of California, San Diego. The author has contributed to research in topics: Carbene & Catalysis. The author has an hindex of 7, co-authored 10 publications receiving 304 citations. Previous affiliations of Daniel R. Tolentino include California State University, Northridge.
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Journal ArticleDOI
Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction".
TL;DR: It is demonstrated that although mono- and bis-copper complexes promote the CuAAC reaction, the dinuclear species are involved in the kinetically favored pathway.
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Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes.
Cory M. Weinstein,Glen P. Junor,Daniel R. Tolentino,Rodolphe Jazzar,Mohand Melaimi,Guy Bertrand +5 more
TL;DR: Cyclic (alkyl)(amino)carbenes with a six-membered backbone were prepared and feature increased % Vbur and enhanced donor and acceptor properties, as evidenced by the observed n → π* transition trailing into the visible region.
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Mesoionic Carbene‐Gold(I) Catalyzed Bis‐Hydrohydrazination of Alkynes with Parent Hydrazine
TL;DR: A novel synthetic route gives access to mesoionic carbene and cyclopropenylidene supported gold chloride complexes, allowing for the first transition metal-catalyzed functionalization of both nitrogens of parent hydrazine.
Journal ArticleDOI
Reductive Elimination at Carbon under Steric Control.
Daniel R. Tolentino,Samuel E. Neale,Connie J. Isaac,Stuart MacGregor,Michael K. Whittlesey,Rodolphe Jazzar,Guy Bertrand +6 more
TL;DR: It is shown that, as is the case with transition metals, the steric environment can be used to promote reductive elimination at carbon centers.
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Realizing Metal-Free Carbene-Catalyzed Carbonylation Reactions with CO
Jesse L Peltier,Eder Tomás-Mendivil,Eder Tomás-Mendivil,Daniel R. Tolentino,Max M. Hansmann,Rodolphe Jazzar,Guy Bertrand +6 more
TL;DR: It is reported that a stable singlet ambiphilic carbene activates CO and catalytically promotes thecarbonylation of an o-quinone into a cyclic carbonate, paving the way for the discovery of metal-free catalyzed carbonylation reactions.