D
Daniele Zuccaccia
Researcher at University of Udine
Publications - 82
Citations - 3520
Daniele Zuccaccia is an academic researcher from University of Udine. The author has contributed to research in topics: Catalysis & Counterion. The author has an hindex of 35, co-authored 79 publications receiving 3228 citations. Previous affiliations of Daniele Zuccaccia include University of Perugia & University of Bologna.
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Determining accurate molecular sizes in solution through NMR diffusion spectroscopy
TL;DR: The methodological procedures that can be used to obtain accurate molecular sizes in solution from diffusion NMR spectroscopy, and how to take into account the size of the solute with respect to that of the solvent and its non-spherical shape using the appropriate correction factors in the frictional coefficient are reviewed.
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An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2.
Leah N. Appelhans,Daniele Zuccaccia,Anes Kovacevic,Anthony R. Chianese,John R. Miecznikowski,Alceo Macchioni,Eric Clot,Odile Eisenstein,Robert H. Crabtree +8 more
TL;DR: PGSE NMR experiments support the formation of ion-pair in both the reactants and the products that is consistent with the computational prediction (ONIOM(B3PW91/UFF)).
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Iridium(III) molecular catalysts for water oxidation: the simpler the faster.
Arianna Savini,Gianfranco Bellachioma,Gianluca Ciancaleoni,Cristiano Zuccaccia,Daniele Zuccaccia,Alceo Macchioni +5 more
TL;DR: It is remarkable that 3, having the simplest structure, is the catalyst with the highest activity.
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Activity and degradation pathways of pentamethyl-cyclopentadienyl-iridium catalysts for water oxidation
Arianna Savini,Paola Belanzoni,Gianfranco Bellachioma,Cristiano Zuccaccia,Daniele Zuccaccia,Alceo Macchioni +5 more
TL;DR: The activity of three archetypal catalysts for water oxidation to molecular oxygen was compared using cerium(IV) ammonium nitrate as a sacrificial oxidant in this paper, and it was observed that Cp* underwent an oxidative degradation, ultimately leading to acetic, formic and glycolic acids.
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How π back-donation quantitatively controls the CO stretching response in classical and non-classical metal carbonyl complexes
Giovanni Bistoni,Sergio Rampino,Nicola Scafuri,Gianluca Ciancaleoni,Daniele Zuccaccia,Leonardo Belpassi,Francesco Tarantelli +6 more
TL;DR: It is definitively show that the CO stretching response to metal coordination is driven exclusively by π polarization, which quantitatively correlates with π back-donation and changes in CO bond length and frequency.