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Diane K. Smith

Researcher at San Diego State University

Publications -  46
Citations -  1381

Diane K. Smith is an academic researcher from San Diego State University. The author has contributed to research in topics: Redox & Electron transfer. The author has an hindex of 18, co-authored 45 publications receiving 1249 citations.

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Voltammetry of quinones in unbuffered aqueous solution: reassessing the roles of proton transfer and hydrogen bonding in the aqueous electrochemistry of quinones

TL;DR: Cyclic voltammetry studies are reported for two representative quinones, benzoquinone and 2-anthraquinonesulfonate, in buffered and unbuffered aqueous solution at different pH's to unify quinone electrochemistry by bridging the apparent gap between the redox chemistry of quinONES in water and that in aprotic organic solvents.
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Electrochemically controlled hydrogen bonding. o-Quinones as simple redox-dependent receptors for arylureas.

TL;DR: In this paper, 9,10-Phenanthrenequinone and acenaphthenequinone are shown to act as simple redox-dependent receptors toward aromatic ureas in CH(2)Cl(2), and DMF.
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Electrochemically controlled hydrogen bonding. Nitrobenzenes as simple redox-dependent receptors for arylureas

TL;DR: Computer fitting of the cyclic voltammetry of 4-nitroaniline, NA, plus 1,3-diphenylurea in DMF shows essentially no binding between urea and NA in the oxidized state, but very strong binding in the reduced state, along with very rapid rates of hydrogen bond formation, making this system a fast on/off redox switch.