E
Ezio Rizzardo
Researcher at Commonwealth Scientific and Industrial Research Organisation
Publications - 197
Citations - 24901
Ezio Rizzardo is an academic researcher from Commonwealth Scientific and Industrial Research Organisation. The author has contributed to research in topics: Radical polymerization & Chain transfer. The author has an hindex of 51, co-authored 197 publications receiving 23712 citations. Previous affiliations of Ezio Rizzardo include University of Melbourne & Kyoto University.
Papers
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Journal ArticleDOI
The detection of preferred conformations in oligomers of methyl methacrylate in solution by 1H n.m.r. 2D-correlation spectroscopy
Paul Cacioli,D. G. Hawthorne,Stanley R. Johns,David H. Solomon,Ezio Rizzardo,Richard I. Willing +5 more
TL;DR: The observation of four bond, extended W pathway connectivities between specific protons of the methylene and methyl groups in methyl methacrylate oligomers (1) −(6) by 1H n.m.r.
Journal ArticleDOI
Initiation Mechanisms in Radical Polymerization: Reaction of t-Butoxy radicals with Allyl methacrylate
TL;DR: The radical-trapping technique employing 1,1,3,3-tetramethylisoindolin-2-yloxyl as scavenger has been used to study the reactions of t-butoxy radicals with allyl methacrylate.
Journal ArticleDOI
Initiation Mechanisms for Radical Polymerization of Methyl Methacrylate with tert-Butyl Peroxypivalate
TL;DR: The reaction of tert-butyl peroxypivalate (2) with methyl methacrylate (3) has been studied by the radical trapping technique employing 1,1,3,3-tetramethyl-2,3dihydro-1H-isoindol-2-yloxyl (1) as a scavenger as mentioned in this paper.
Book ChapterDOI
Chapter 1:The History of Nitroxide-mediated Polymerization
Graeme Moad,Ezio Rizzardo +1 more
TL;DR: In this article, the early history of nitroxide-mediated polymerization (NMP) during the first ∼15 years is described, with a short prehistory of observations, made during studies on defining initiation mechanisms using nitroxides radical trapping that can be seen to have inspired the initial experiments.
Journal ArticleDOI
Developments in the synthesis of maleated polyolefins by reactive extrusion
Tracey Bray,Sam Damiris,Andrew Grace,Graeme Moad,Michael Shane O'shea,Ezio Rizzardo,Gary van Diepen +6 more
TL;DR: In this paper, the maleation of linear low density polyethylenes by reactive extrusion has been explored with a view to defining the conditions necessary for a robust process that provides both high grafting efficiencies (>80%) and minimal degradation or cross-linking.