Industries such as the automotive, aerospace or military, as well as environmental and biological research have promoted the development of ultraviolet (UV) photodetectors capable of operating at high temperatures and in hostile environments. UV-enhanced Si photodiodes are hence giving way to a new generation of UV detectors fabricated from wide-bandgap semiconductors, such as SiC, diamond, III-nitrides, ZnS, ZnO, or ZnSe. This paper provides a general review of latest progresses in wide-bandgap semiconductor photodetectors.

https://iopscience.iop.org/article/10.1088/0268-1242/18/4/201/pdf

Wide-bandgap semiconductor ultraviolet photodetectors

Recent development in 2D materials beyond graphene

In this report, we demonstrate high spectral responsivity (SR) in MBE grown epitaxial beta-Ga2O3-based solar blind metal-semiconductor-metal (MSM) photodetectors (PD). The (-201)-oriented beta-Ga2O3 thin film was grown using plasma-assisted MBE on c-plane sapphire substrates. MSM devices fabricated with Ni/Au contacts in an interdigitated geometry were found to exhibit peak SR > 1.5 A/W at 236-240 nm at a bias of 4V with a UV to visible rejection ratio > 10(5). The devices exhibited very low dark current 10(3). These results represent the state-of-art performance for the MBE-grown beta-Ga2O3 MSM solar blind detector. Published by AIP Publishing.

High responsivity in molecular beam epitaxy grown beta-Ga2O3 metal semiconductor metal solar blind deep-UV photodetector

Novel self-powered nanoscale photodetectors that can work without an external power source, which have great application potential in next-generation nanodevices that operate wirelessly and independently, are being widely studied. This review aims to give a comprehensive summary of the state-of-the-art research results on self-powered nanoscale photodetectors. An introduction of recent progress on Schottky junction photodetectors is provided. Two types of Schottky junctions are discussed in detail: metal-semiconductor and semiconductor-graphene junctions. Next, recent developments of p-n junction photodetectors are highlighted, including homojunction and heterojunction photodetectors. Then, piezo-phototronic effect enhanced photodetection performances of Schottky junctions and p-n junctions are discussed. Then, significant results on the photoelectrochemical-cell-based photodetector and integrated self-powered nanosystem are presented, followed by a systematic comparison of different types of photodetectors. Finally, a summary of the previous results is given, and the major challenges that need to be addressed in the future are outlined. The hope is that this review can provide valuable insights into the current status of self-powered photodetectors and spur new structure and device designs to further enhance photodetection performance.

https://www.onlinelibrary.wiley.com/doi/pdf/10.1002/smll.201701848

Self-Powered Nanoscale Photodetectors.

With the fast development of nanoscience and nanotechnology in the last 30 years, semiconductor nanowires have been widely investigated in the areas of both electronics and optoelectronics. Among them, representatives of third generation semiconductors, such as ZnO and GaN, have relatively large spontaneous polarization along their longitudinal direction of the nanowires due to the asymmetric structure in their c-axis direction. Two-way or multiway couplings of piezoelectric, photoexcitation, and semiconductor properties have generated new research areas, such as piezotronics and piezo-phototronics. In this review, an in-depth discussion of the mechanisms and applications of nanowire-based piezotronics and piezo-phototronics is presented. Research on piezotronics and piezo-phototronics has drawn much attention since the effective manipulation of carrier transport, photoelectric properties, etc. through the application of simple mechanical stimuli and, conversely, since the design of new strain sensors based on the strain-induced change in semiconductor properties.

Piezotronics and Piezo-phototronics of Third Generation Semiconductor Nanowires.

The fabrication and characterization of ultraviolet photodetectors based on GaN p-n junctions is reported. The devices are grown by metalorganic vapour phase epitaxy on basal-plane sapphire substrates. These detectors are visible-blind with a sharp wavelength cut-off at 360 nm. The photocurrent is linear with incident power from up to , with a responsivity of at 360 nm. The device time response is dominated by the effective resistance-capacitance time constant, and a 105 ns response is estimated for very low load resistances. A comparison with the response of GaN photoconductor detectors is also presented. The application of these high-performance photodetectors for solar ultraviolet monitoring is described.

https://iopscience.iop.org/article/10.1088/0268-1242/13/9/013/pdf

High-performance GaN p-n junction photodetectors for solar ultraviolet applications

Schottky barrier photovoltaic detectors based on Si-doped AlxGa1−xN (0 ≤ x ≤ 0.22) have been fabricated and characterized. Samples were grown on basal plane sapphire by LP-MOVPE. Schottky contacts were made with Au. Responsivities are independent of the diode size and of the incident power in the range measured (10mW/m2 to 2KW/m2). The spectral response shows an abrupt cutoff that shifts linearly to higher energy with increasing Al content. A visible rejection of 3 to 4 orders of magnitude is observed in AlxGa1−xN Schottky photodiodes. Device time response is RC-limited, and a minimum decay time as short as 15ns have been estimated in unbiased Al0.22Ga0.28N diodes. This time response can be further reduced by reverse biasing.

/pdf/ultraviolet-photodetectors-based-on-alxga1-xn-schottky-yknfvbk0z7.pdf

F. Cusso

Papers

High-performance GaN p-n junction photodetectors for solar ultraviolet applications

Ultraviolet Photodetectors Based on AlxGa1-xN Schottky Barriers