F
Fernando Blanco
Researcher at University of Valencia
Publications - 18
Citations - 515
Fernando Blanco is an academic researcher from University of Valencia. The author has contributed to research in topics: Aryl & Deprotonation. The author has an hindex of 10, co-authored 18 publications receiving 495 citations. Previous affiliations of Fernando Blanco include Spanish National Research Council & University College Dublin.
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Journal ArticleDOI
Competition of Hydrogen Bonds and Halogen Bonds in Complexes of Hypohalous Acids with Nitrogenated Bases
TL;DR: Two minima complexes are found, one with an OH...N hydrogen bond and the other one with a X...N halogen bond, and the first one is more stable for the smallest halogen derivatives.
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Deprotonation of Benzoxazole and Oxazole Using Lithium Magnesates
Omar Bayh,Haçan Awad,Florence Mongin,Christophe Hoarau,Laurent Bischoff,François Trécourt,Guy Quéguiner,Francis Marsais,Fernando Blanco,Belén Abarca,Rafael Ballesteros +10 more
TL;DR: The isolation of 2-substituted oxazoles and benzoxazoles in medium to good yields after electrophilic trapping was interpreted in two ways: the equilibration between the open and closed structures is faster than the trapping of the open isomers, and the closed isomers are more reactive than the open ones.
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Deprotonation of fluoro aromatics using lithium magnesates
Haçan Awad,Florence Mongin,François Trécourt,Guy Quéguiner,Francis Marsais,Fernando Blanco,Belén Abarca,Rafael Ballesteros +7 more
TL;DR: In this paper, 3-fluoropyridine was deprotonated with 1/3-equiv of the highly coordinated magnesate Bu 4 MgLi 2 in THF at −10°C in the presence of a substoichiometric amount of 2,2,6,6-tetramethylpiperidine.
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Deprotonation of thiophenes using lithium magnesates
Omar Bayh,Haçan Awad,Florence Mongin,Christophe Hoarau,François Trécourt,Guy Quéguiner,Francis Marsais,Fernando Blanco,Belén Abarca,Rafael Ballesteros +9 more
TL;DR: In this article, Li-Arylmagnesate was either trapped with electrophiles or cross-coupled in a one-pot procedure with aryl halides under palladium catalysis.
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3-(2-Pyridyl)-[1,2,3]triazolo[1,5-a]pyridines. An experimental and theoretical (DFT) study of the ring–chain isomerization
Belén Abarca,Ibon Alkorta,Rafael Ballesteros,Fernando Blanco,Mimoun Chadlaoui,José Elguero,Fatemeh Mojarrad +6 more
TL;DR: The experimental results as well as the calculations lead to the conclusion that the A-B ratio depends on the electronic properties of the substituents.