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Flemming Heinen
Researcher at Ruhr University Bochum
Publications - 9
Citations - 418
Flemming Heinen is an academic researcher from Ruhr University Bochum. The author has contributed to research in topics: Halogen bond & Lewis acids and bases. The author has an hindex of 6, co-authored 9 publications receiving 238 citations.
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Iodine(III) Derivatives as Halogen Bonding Organocatalysts
TL;DR: First strong indications for the crucial role of halogen bonding in this kind of catalyses are presented, including the solvolysis of benzhydryl chloride and the Diels-Alder reaction of cyclopentadiene with methyl vinyl ketone.
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A bidentate iodine(III)‐based halogen‐bond donor as a powerful organocatalyst
TL;DR: The first application of a bidentate bis(iodolium) salt as organocatalyst in a Michael and a nitro‐Michael addition reaction as well as in a Diels–Alder reaction that had not been activated by noncovalent organoc atalysts before.
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Hypervalent Iodine(III) Compounds as Biaxial Halogen Bond Donors
TL;DR: This work presents the first systematic investigation on biaxial binding to such Lewis acids in solution through 1H NMR spectroscopy and isothermal titration calorimetry on iodine(III) derivatives.
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Activation of a Metal-Halogen Bond by Halogen Bonding
Julian Wolf,Florian Huber,Nikita Erochok,Flemming Heinen,Vincent Guérin,Claude Y. Legault,Stefan F. Kirsch,Stefan M. Huber +7 more
TL;DR: The role of halogen bonding in the activation of metal‐halogen bonds was further investigated by NMR experiments and DFT calculations, which support the mode of activation occurring via halogen Bonding.
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Refined SMD Parameters for Bromine and Iodine Accurately Model Halogen-Bonding Interactions in Solution.
Elric Engelage,Nils Schulz,Flemming Heinen,Stefan M. Huber,Donald G. Truhlar,Christopher J. Cramer +5 more
TL;DR: The SMD18 model is used to compare hydrogen bonding to halogen bonding and to reassess the interpretation of recent experiments to calculate liquid-phase free energies of species and equilibria involving halogen Bonding.