Francesc Mas

TL;DR: A thermodynamic formalism to describe the small molecule-macromolecule complexation equilibrium, based on the concept of free and occupied sites (formal species) is presented in this paper.

TL;DR: In this paper, a detailed study of the behavior of usual complexation isotherms with different underlying affinity spectra at intermediate and low coverages is performed, showing that, at intermediate coverages, the value of Kc depends basically on the average, μ, and standard deviation, σ, of the distribution function p(log k), the binding curve showing low sensitivity with respect to the concrete shape of the affinity spectrum.

TL;DR: The interpretation of the normal-pulse polarographic (NPP) and the reverse-pulses polarographic reduction of a metal ion with induced reactant adsorption in a labile metal-macromolecular system for any ligand-to-metal ratio is discussed in this paper.

TL;DR: In this paper, the diffusion of tracer particles in 3D macromolecular crowded media has been studied using two methodologies, simulation and experimental, with the aim of comparing their results.

TL;DR: In this article, a rigorous theory is developed to obtain a current potential time relationship when an arbitrary potential is applied to the DME and a reversible diffusion-controlled reaction occurs with adsorption of both reactant and product of the reaction.